[PDF] Top 20 Dynamic Nuclear Polarization Opens New Perspectives for NMR Spectroscopy in Analytical Chemistry

... of NMR. While DNP-MAS NMR is already a technique which has reinforced the applicability of conventional MAS NMR by addressing previously unsolvable problems, the applications of dissolution DNP are ... Voir le document complet

... allowed for the collection of 2D experiments within a few hours using ~14–20 μl of ...improvement in resolution for the biosilica-entrapped AS-SOD enzyme when moving from 5 to ...shown in ... Voir le document complet

... Dissolution dynamic nuclear polarization (d-DNP) is a versatile method to enhance nuclear magnetic reso- nance (NMR) ...and in-cell investigations. This perspectives ... Voir le document complet

... ynamic nuclear polarization (DNP) has recently developed into a promising approach to greatly increase the sensitivity of solid-state NMR ...μw)-driven polarization transfer from unpaired ... Voir le document complet

... environments, for example the differentiation of surface and core species of hydroxyapatite nanoparticles, can be obtained using solid-state NMR, when combined with dynamic nuclear ...ideal ... Voir le document complet

... metabolites, for the sake of clarity in the ...groups in the score plot, and in the loading plot, the buckets responsible for the group separation come from the same biomarkers ... Voir le document complet

... 2D NMR, 802 Food ...with in-line monitoring 804 using benchtop NMR spectroscopy, ...Benchtop NMR for the 806 monitoring of bioprocesses, ...methods, in: ...809 ... Voir le document complet

... tracted with diethyl ether (2 x 10 mL) and the combined organic layers were washed several times with water and once with brine, before being dried over sodium sulfate[r] ... Voir le document complet

... intense in ufCOSY while some are more intense in ufDQS (see SI); the detailed analysis of peak volumes in ultrafast spectra is a complex and ongoing ...two new pulse sequences for ... Voir le document complet

... shown in Figure ...different nuclear spin-noise shapes (not always pure in-phase Lorentzian) even if FSTO condition (Equation ...even for low temperature noise, appears much higher than the ... Voir le document complet

... of Chemistry, Brandeis University, Waltham, MA 02454, USA Abstract We describe the design and implementation of a novel tunable 250 GHz gyrotron oscillator with >10 W output power over most of a 3 GHz band and ... Voir le document complet

... observed for 2 (Fig. 4b). We envisaged two possible mechanisms to account for the chemical exchange behaviour of 2 that would be inaccessible or less likely to occur for 1 (Scheme ...system. ... Voir le document complet

... way in which the ionic charge is developed inside the micropores in the electrode as it charges differs depending on the properties of the ...obtained for the NEt 4 –BF 4 electrolyte show that the ion ... Voir le document complet

... a new analytical equation is ...allows analytical explanation of the difference of tuning conditions [2,3] and the treatment of static magnetic field inhomogeneity, which has an enhanced spectral ... Voir le document complet

... pulse in multiple scans is used to unfold spectral ...position in k-space, and instead assigns arbitrary k-space positions to selected frequency ...developed for MRI applications to perform water/fat ... Voir le document complet

... archive for the deposit and dissemination of sci- entific research documents, whether they are pub- lished or ...institutions in France or abroad, or from public or private research ... Voir le document complet

... As part of data processing, and because untargeted screening relies on the relative quantification, a proper normalization is required prior to any data mining. Z-score and probabilistic quotient normalization are often ... Voir le document complet

... O pen A rchive T OULOUSE A rchive O uverte ( OATAO ) OATAO is an open access repository that collects the work of Toulouse researchers and makes it freely available over the web where possible. This is an ... Voir le document complet

... (USFDA) for use as inactive ingredients in oral tablets and ...glucose in cellulose is flipped over due to the β -1,4 linkages, which promotes intrachain and interchain hydrogen bonds, as well as van ... Voir le document complet

... F NMR spectroscopy has been used to study the local environments of anions in supercapacitor electrodes and to quantify changes in the populations of adsorbed species during ...charging. ... Voir le document complet