Metal-organic
Mixed-metal metal–organic frameworks
... Mixed-metal Metal-Organic Frameworks Sara Abednatanzi a,† , Parviz Gohari Derakhshandeh a,† , Hannes Depauw a , François-Xavier Coudert b , Henk Vrielinck c , Pascal Van Der Voort* a,d and Karen ...
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Metal–organic framework with color-switching and strongly polarized emission
... as metal− organic frameworks (MOFs) and metal−ion complexes in which the luminescence properties such as emission wave- length and polarization states can be ...
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TiOxNy coatings grown by atmospheric pressure metal organic chemical vapor deposition
... pressure metal organic chemical vapor deposition (MOCVD) process using titanium tetra-iso-propoxide as titanium and oxygen precursors and hydrazine as a nitrogen ...
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Cooperative insertion of CO2 in diamine-appended metal-organic frameworks
... the metal-amine coordinate bond must be capable of ...open metal sites within the pores of the metal-organic frame- work, is ...of metal-organic frame- work materials would be ...
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Rich Polymorphism of a Metal–Organic Framework in Pressure–Temperature Space
... ¶ Department of Materials Sciences & Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge CB3 0FS, U.K. * S Supporting Information ABSTRACT: We present an in situ powder X-ray di ffraction study on ...
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Thermodynamic Methods and Models to Study Flexible Metal-Organic Frameworks
... 3.4 Out of equilibrium: a stress-based model Finally, we shall say here a few words here about the out-of- equilibrium states of soft porous crystals, their relevance to the understanding of experimental data and ...
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Microscopic Mechanism of Chiral Induction in a Metal–Organic Framework
... Recently, Zaworotko and coworkers 7 reported the exciting preparation of a chiral polymorph of the prototypical metal–organic framework MOF-5 (also known as IRMOF-1). 8 This was achieved by conducting ...
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Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks
... porous metal −organic frameworks (MOFs) in electronic devices are rare, owing in large part to a lack of MOFs that display electrical ...volatile organic compounds ...
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Carbon dioxide sensing with 2D conductive metal-organic frameworks
... Carbon Dioxide Gas Detection by Open Metal Site Metal Organic Frameworks and Surface Functionalized Metal Organic Frameworks. A Metal-Organic Framework-Based Material f[r] ...
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Pressure promoted low-temperature melting of metal–organic frameworks
... Conclusion The P-T phase diagram of the metal-organic frameworks ZIF-4 and ZIF-62 have been created by combining in-situ X-ray diffraction and optical microscopy with thermodynamic considerations. ...
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Synthesis and characterization of nanoporous materials: nanozeolites and metal-organic frameworks
... and metal-organic frameworks were ...an organic solvent containing organosilane to the aqueous zeolite gel solution, resulting in a two-phase ...the organic phase whereas, large zeolite ...
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Rotational Dynamics of Linkers in Metal–Organic Frameworks
... in metal–organic frameworks from a computational ...the organic linker in IRMOF-1 (= MOF-5) of 34 kJ mol −1 , a value significantly lower than that calculated by Zhou, and which can be attributed to ...
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Pillared sulfonate-based metal-organic framework as negative electrode for Li-ion batteries
... Metal Organic Frameworks (MOFs) have proven to be very versatile materials due to the great number of metallic clusters or organic ligands that can be used in the construction of these ...of ...
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Modelling photophysical properties of metal–organic frameworks: a density functional theory based approach
... within metal-organic frameworks (MOFs) is a subject of ever increasing attention in recent years with theoretical approaches poised to play a key role alongside experiment in both the understanding of ...
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Heterogenisation of polyoxometalates and other metal-based complexes in metal–organic frameworks: from synthesis to characterisation and applications in catalysis
... as metal complexes with oxo ligands with a large domain of ...as Metal-Organic Frameworks (MOFs) has thus emerged in the recent years as an attractive strategy to address these drawbacks and develop ...
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Aluminum-Based Metal–Organic Frameworks Derived Al 2 O 3 -Loading Mesoporous Carbon as a Host Matrix for Lithium-Metal Anodes
... lithium metal, metal−organic frameworks (MOFs) as a relatively new class of crystalline porous materials with high specific surface area, wide structural diversity, and easy tailorability, have also ...
10
TiOxNy coatings grown by atmospheric pressure metal organic chemical vapor deposition
... pressure metal organic chemical vapor deposition (MOCVD) process using titanium tetra-iso-propoxide as titanium and oxygen precursors and hydrazine as a nitrogen ...
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Insulator-to-Proton-Conductor Transition in a Dense Metal–Organic Framework
... ABSTRACT: Metal-organic frameworks (MOFs) are prone to exhibit phase transitions under stimuli such as changes in pressure, temperature or gas-sorption because of their flexible and responsive ...
6
Cation exchange at the secondary building units of metal–organic frameworks
... a metal ion at the site of ...nanocrystals. Metal–organic frameworks (MOFs) emerged decades ago, but cation exchange was only first demonstrated with them in ...
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Adsorption Contraction Mechanics: Understanding Breathing Energetics in Isoreticular Metal–Organic Frameworks
... New Metal-Organic Framework with Ultra-high Surface ...Porous Metal- Organic Framework, Constructed from a Cuboctahedral Super-molecular Building Block, with Exceptionally High Methane ...
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