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Fluoroalkyl Pentacarbonylmanganese(I) Complexes as Initiators for the Radical (co)Polymerization of Fluoromonomers

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Academic year: 2021

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Table 1. Results for the VDF polymerization initiated by the thermal or photochemical activations of 1.
Figure 1. First-order kinetics plot for the polymerization of VDF in the presence of [Mn(CF 3 )(CO) 5 ]  initiated thermally (100 °C)
Figure 2. Plots of the number of average molar masses and dispersities vs. conversion of VDF  polymerization initiated by UV irradiation in the presence of [Mn(CF 3 )(CO) 5 ]
Figure 3.  1 H NMR spectrum (400 MHz, DMF-d 7 ) between 0 and 10 ppm of the PVDF obtained by  thermal activation of 1 (entry 7 of Table 1)
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