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Locking and Unlocking the Molecular Spin Crossover Transition

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Academic year: 2021

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Figure 2. Schematics of the principle of reversible control of the spin state of molecule 1, pinned in  the majority LS state in the presence of molecule 2 at temperatures reaching room temperature (RT)
Figure 3. (a) Temperature dependent X-ray absorption spectra of molecule 1 powder; (b) Time  evolution of a 5 nm thick films of molecule 1 on SiO 2  at a constant temperature of 290 K
Figure 4. X-ray absorption spectra of thin films of molecule 1 on SiO 2  (a-c) and on Al 2 O 3  (d), indicating  time evolution of SOXIESST at (a) 200 K, (b) 290 K and (c) 345 K, for 5 nm thick films on SiO 2
Figure 6. X-ray absorption spectra showing the ‘unlocking’ of 5 nm thin films of molecule 1 on SiO 2 ,  under soft X-ray fluences (SOXIESST on), towards a HS state within about 5 min at 290 K
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