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Tuning the Reactivity of a Heterogeneous Catalyst using N‐Heterocyclic Carbene Ligands for C−H Activation Reactions

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Academic year: 2021

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Figure

Figure 1: Schematic preparation of the NHCs modified Ru on carbon catalysts and examples of catalytic activity  switchs observed
Table 1: Initial screening of conditions, catalysts and ligands for the H/D exchange on 1-dodecanol
Figure 2: Illustration of catalytic activity switches in the context of the deuterium labelling of aliphatic alcohols  and N-heterocycles
Figure  3:  Illustration  of  the  dramatic  impact  of  the  addition  of  NHC  (1  eq)  on  the  chemical  outcome  in  the  context  of  the  deuteration  of  easily  reducible  compounds  13  to  16
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