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Mössbauer characterisations and magnetic properties of iron cobaltites CoxFe3−xO4 (1 ≤ x ≤ 2.46) before and after spinodal decomposition

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Fig. 1. SEM images of (a) oxalate (Co 1.73 Fe 1.27 ) 1/3 C 2 O 4 2H 2 O and (b) oxide Co 1.73 Fe 1.27 O 4 and (c) XRD pattern of Co 1.73 Fe 1.27 O 4 powder quenched at 900 1C and annealed at 700 1 C 36 h and 120 h.
Fig. 3. M ¨ossbauer spectra measured at 5 K with an applied magnetic field of 60 kOe for Co x Fe 3ÿx O 4 powders (1.00 r x r 2.46) quenched at 900 1C.
Fig. 4. Saturation magnetization (M S ) of Co x Fe 3ÿx O 4 (x¼1.00, 1.22, 1.73, and 2.46) quenched at 900 1 C, measured at 5 K and calculated at 0 K
Fig. 5. M ¨ossbauer spectra measured at 300 K and 5 K with an applied magnetic field of 60 kOe for Co 1.73 Fe 1.27 O 4 powder after spinodal decomposition by  anneal-ing at 700 1C for 120 h.
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