Pierre-Gilles de Gennes Pierre-Gilles de Gennes
and the puzzle of supersolidity and the puzzle of supersolidity
Sébastien Balibar
Sébastien Balibar , Frédéric Caupin , Frédéric Caupin and Satoshi Sasaki
and Satoshi Sasaki
Laboratoire de Physique Statistique (ENS-Paris) Laboratoire de Physique Statistique (ENS-Paris)
De Gennes Days, 16 May 2008 De Gennes Days, 16 May 2008 for references, articles and movies, see :
for references, articles and movies, see : http://www.lps.ens.fr/~balibar/http://www.lps.ens.fr/~balibar/
PG de Gennes PG de Gennes
9 / 02 / 1995 9 / 02 / 1995
« « Le Palais de la Découverte Le Palais de la Découverte est l'un des grands centres européens est l'un des grands centres européens d'initiation à la science. Installé avenue Franklin-Roosevelt, depuis d'initiation à la science. Installé avenue Franklin-Roosevelt, depuis sa fondation par Jean Perrin en 1937, il a marqué des générations sa fondation par Jean Perrin en 1937, il a marqué des générations de lycéens. Nous sommes nombreux à y avoir découvert notre
de lycéens. Nous sommes nombreux à y avoir découvert notre
passion pour la recherche grâce à des expériences simples et bien passion pour la recherche grâce à des expériences simples et bien expliquées.
expliquées.
L'expulsion du Palais de son bâtiment serait un désastre. » L'expulsion du Palais de son bâtiment serait un désastre. » le Palais est en danger, à nouveau. Appel sur
le Palais est en danger, à nouveau. Appel sur http://www.sauvonslepalaisdeladecouverte.fr/
http://www.sauvonslepalaisdeladecouverte.fr/
Trieste, May 2006
Trieste, May 2006
Trieste, May 2006
Trieste, May 2006
Trieste, May 2006
Trieste, May 2006
Trieste, May 2006
Trieste, May 2006
Trieste, May 2006
Trieste, May 2006
Trieste, May 2006
Trieste, May 2006
what was Pierre-Gilles talking about ?
... as a possible ... as a possible explanation for explanation for Kim and Chan’s Kim and Chan’s
astonishing astonishing
proposal proposal
Nature 427, 225 (2004) Nature 427, 225 (2004)
some of his some of his most recent most recent
ideas...
ideas...
a « supersolid » is a solid ...
... which is also superfluid !
a solid a solid : :
transverse elasticity transverse elasticity
non zero shear modulus non zero shear modulus
a consequence of atom localization a consequence of atom localization
crystals - glasses crystals - glasses a superfluid
a superfluid : :
a quantum fluid with zero viscosity a quantum fluid with zero viscosity
a consequence of « Bose-Einstein condensation » a consequence of « Bose-Einstein condensation »
atoms are undistinguishable and delocalized atoms are undistinguishable and delocalized a paradoxical idea
a paradoxical idea
Could a solid flow like a superfluid ?
E. Kim and M. Chan (Penn. State U. 2004):
E. Kim and M. Chan (Penn. State U. 2004):
a torsional oscillator (
a torsional oscillator (~1 kHz)~1 kHz)
a change in the period of oscillation a change in the period of oscillation below
below ~1~100 mK00 mK
1 % of the solid mass decouples from the 1 % of the solid mass decouples from the oscillating walls ?
oscillating walls ?
Be-Cu
Torsion Rod Torsion Bob containing helium
Drive
Detection
K I
o
π
τ = 2
some early theoretical ideas
Andreev and Lifshitz 1969:
Andreev and Lifshitz 1969:
delocalized defects (vacancies) could exist at T=0 delocalized defects (vacancies) could exist at T=0 ( the crystal would be « incommensurate »)
( the crystal would be « incommensurate ») tunneling frequency
tunneling frequency , coordination number z, coordination number z the bottom of the band could be negative the bottom of the band could be negative
BEC => a fraction of the mass is superfluid => superplasticity BEC => a fraction of the mass is superfluid => superplasticity
EE00 2 z h2 z h
Penrose and Onsager 1956:
Penrose and Onsager 1956:
generalize Bose Einstein Condensation (BEC) to condensed matter systems generalize Bose Einstein Condensation (BEC) to condensed matter systems Off diagonal long range order in the density matrix
Off diagonal long range order in the density matrix BEC is impossible in a solid
BEC is impossible in a solid
(but they used non-symmetrized wave fonctions) (but they used non-symmetrized wave fonctions)
Reatto and Chester 1969: some models of Q-solids show BEC Reatto and Chester 1969: some models of Q-solids show BEC symmetry of the wave function ?
symmetry of the wave function ? overlap is necessary
overlap is necessary (Imry and Schwartz 1975)(Imry and Schwartz 1975) a large class of Q-solids do NOT show BEC a large class of Q-solids do NOT show BEC Leggett 1970:
Leggett 1970:
non-classical rotation inertia (NCRI) if atoms are delocalized (if there are free vacancies ?) non-classical rotation inertia (NCRI) if atoms are delocalized (if there are free vacancies ?)
some recent theoretical ideas
Prokofev , Svistunov, Boninsegni, et al. 2005-6 (MC calc.):
Prokofev , Svistunov, Boninsegni, et al. 2005-6 (MC calc.):
no BEC in crystals without free vacancies ;
no BEC in crystals without free vacancies ; 44He crystals are commensurate (EHe crystals are commensurate (Evacvac = 13K) = 13K) BEC is possible in a
BEC is possible in a 44He glass (Boninsegni et al. PRL 2006)He glass (Boninsegni et al. PRL 2006)
controversies with Galli and Reatto 2006 , Clark and Ceperley, Cazorla and controversies with Galli and Reatto 2006 , Clark and Ceperley, Cazorla and Boronat, etc.
Boronat, etc.
possible analogies with the Hubbard model and cold atoms in optical lattices possible analogies with the Hubbard model and cold atoms in optical lattices see I. Bloch, J. Dalibard and W. Zwerger, Rev. Mod. Phys. 2008
see I. Bloch, J. Dalibard and W. Zwerger, Rev. Mod. Phys. 2008
Anderson Brinkman and Huse (Science 2005): 4He crystals are incommensurate ! Anderson Brinkman and Huse (Science 2005): 4He crystals are incommensurate ! a new analysis of the lattice parameter
a new analysis of the lattice parameter a/a (T) and specific heat Ca/a (T) and specific heat Cvv(T)(T)
not confirmed by new neutron scattering measurements (Blackburn et al. PRB 2007) not confirmed by new neutron scattering measurements (Blackburn et al. PRB 2007) criticized by H.J. Maris and S. Balibar (J. Low Temp. Phys. 147, 539, 2007)
criticized by H.J. Maris and S. Balibar (J. Low Temp. Phys. 147, 539, 2007) Anderson has now switched to a « vortex liquid » model (Nature Physics 2007) Anderson has now switched to a « vortex liquid » model (Nature Physics 2007)
new experiments:
evidence for the importance of disorder
Rittner and Reppy (Cornell, 2006-7):
Rittner and Reppy (Cornell, 2006-7):
annealing destroys supersolid behavior annealing destroys supersolid behavior
quenched cooled crystals : very large « superfluid fraction »
quenched cooled crystals : very large « superfluid fraction » ss up to 20 % up to 20 % more experiments (Aoki and Kojima, Clark and Chan, Shirahama...):
more experiments (Aoki and Kojima, Clark and Chan, Shirahama...):
ss varies from 0.03 to 20% depending on sample preparation varies from 0.03 to 20% depending on sample preparation
Sasaki, Ishiguro, Caupin, Maris et Balibar (ENS, Science 2006) : Sasaki, Ishiguro, Caupin, Maris et Balibar (ENS, Science 2006) : two communicating vessels filled with solid helium
two communicating vessels filled with solid helium superfluid mass transport
superfluid mass transport onlyonly in the presence of grain boundaries in the presence of grain boundaries
PGG (CR Physique 7, 561, 2006):
PGG (CR Physique 7, 561, 2006):
quantum plasticity in a quantum crystal quantum plasticity in a quantum crystal
an edge dislocation an edge dislocation
a weakly bound a weakly bound kink - antikink pair kink - antikink pair
a model at T = 0 : large quantum tunneling of kinks a model at T = 0 : large quantum tunneling of kinks
weak pairing of kink and antikinksweak pairing of kink and antikinks
large mobility of dislocationslarge mobility of dislocations
large mobility of grain boundaries ( « dislocation ladders » )large mobility of grain boundaries ( « dislocation ladders » )
quantum plasticity at T = 0quantum plasticity at T = 0
a change in mechanical properties at some finite T ??a change in mechanical properties at some finite T ??
Pollet et al. PRL 98, 135301, 2007
Grain boundaries are Grain boundaries are ~ ~ 3 atoms thick
3 atoms thick
superfluid for large superfluid for large misorientation
misorientation
not superfluid for small not superfluid for small misorientation
misorientation
edge dislocations are edge dislocations are not superfluid
not superfluid
TTcc ~ 0.2 to 1 K~ 0.2 to 1 K depending on depending on orientation orientation
critical velocity ? critical velocity ?
Boninsegni et al. PRL 99, 035301, 2007 : superfluidity of screw dislocation cores
phase coherence along the core of screw phase coherence along the core of screw dislocations on a distance
dislocations on a distance ~ 1/T~ 1/T a true 1D- supersolid
a true 1D- supersolid
a network of dislocations with density n a network of dislocations with density nss 3D- superfluidity below T
3D- superfluidity below Tcc ~ 1/l ~ n~ 1/l ~ nss1/21/2
in their model, a very large dislocation density in their model, a very large dislocation density would be needed to build a superfluid density would be needed to build a superfluid density of order 0.1%
of order 0.1%
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in blue: local superfluid density in blue: local superfluid density
a Monte Carlo calculation a Monte Carlo calculation
G. Biroli and J.P. Bouchaud preprint 2007 G. Biroli and J.P. Bouchaud preprint 2007
the free energy for the creation of kink-antikink pairs should vanish at T the free energy for the creation of kink-antikink pairs should vanish at Tkk proliferation of kinks
proliferation of kinks
very large transverse fluctuations of dislocations trigger atom exchange in the very large transverse fluctuations of dislocations trigger atom exchange in the bulk solid
bulk solid
supersolidity below some temperature T
supersolidity below some temperature Tcc < T < Tkk
S. Sasaki et al. @ENS Science 313, 1098, 2006
a glass tube (1 cm a glass tube (1 cm ) )
grow a crystal from the superfluid grow a crystal from the superfluid at 1.3 K
at 1.3 K
lower T down to 50 mK lower T down to 50 mK melt the outside => height melt the outside => height difference
difference
follow the level inside
follow the level inside solid heliumsolid helium liquid helium liquid helium
window window
any change in the level inside any change in the level inside requires a mass flow through the requires a mass flow through the solid since
solid since CC = 1.1 = 1.1 LL
if critical velocity v
if critical velocity vcc = 10 = 10 m/s m/s and superfluid density
and superfluid density ss = 10 = 10-2 -2 CC
=> melting velocity V = 3 mm/h
=> melting velocity V = 3 mm/h
1 cm1 cm
filling the tube with solid
filling the tube with solid
44He makes defects He makes defects
solid solid liquid
liquid solidsolid liquidliquid liquid
liquid
the liquid inside the liquid inside crystallizes if a crystallizes if a
substantial stress is substantial stress is applied.
applied.
grain boundaries grain boundaries
grooves at the liquid- grooves at the liquid- solid interface
solid interface
cusps and grain boundaries (GBs)
mechanical equilibrium mechanical equilibrium
of surface tensions of surface tensions
at the liquid-solid interface:
at the liquid-solid interface:
GBGB=2 =2
LS LScos cos
each cusp signals the existence each cusp signals the existence of an emerging grain boundary of an emerging grain boundary
crystal 1 crystal 1 crystal 2
crystal 2
grain boundary grain boundary liquid phase
liquid phase
GBGB22
LSLS
LSLSat Pat Pmm, most cusps move away in , most cusps move away in a few hours a few hours pinning +
pinning + very fast dynamics of grain boundariesvery fast dynamics of grain boundaries some GBs stay pinned on walls
some GBs stay pinned on walls
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without grain boundaries, no flow
If supersolidity was due to a 1% superfluid If supersolidity was due to a 1% superfluid density in the bulk
density in the bulk
with a critical velocity v
with a critical velocity vcc = 10 = 10 m/s m/s the interface should relax at V = 1
the interface should relax at V = 1 m/s, m/s, that is 3.6 mm in 1 hour
that is 3.6 mm in 1 hour
Instead, we see no flow within 50
Instead, we see no flow within 50 m in 4 m in 4 hours, meaning at least 300 times less
hours, meaning at least 300 times less
supersolidity is not due to the superfluidity of a 1% (even 0.03%) supersolidity is not due to the superfluidity of a 1% (even 0.03%) equilibrium density of vacancies moving at 10
equilibrium density of vacancies moving at 10 m/s. m/s.
mass flow in crystals with enough grain boudaries
for 3 crystals with some cusps inside the tube we observed a mass flow for 3 crystals with some cusps inside the tube we observed a mass flow crystal 1 : when the cusp disappears, the mass flow stops
crystal 1 : when the cusp disappears, the mass flow stops
superflow of mass through solid
superflow of mass through solid
44He is associated He is associated with the existence of grain boundaries with the existence of grain boundaries
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crystal 1 relaxed 1 mm down and stopped
crystal 2 : many defects
Many grain boundaries Many grain boundaries more in the lower part more in the lower part faster flow down to faster flow down to equilibrium at h = 0 equilibrium at h = 0
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crystal 2 relaxed down to eq. (h = 0)
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time
time x x 250 250
5 s = 20 min
5 s = 20 min
crystal 2:
crystal 2:
relaxation relaxation
at 50 mK at 50 mK
0.0 2.0 4.0 6.0 8.0
0 500 1000 1500 2000
crystal #2
time t (seconds)
relaxation is not exponential but linear
relaxation is not exponential but linear with two successive regimes, with two successive regimes, constant velocity : 6
constant velocity : 6 m/s for 0 < t < 500 sm/s for 0 < t < 500 s 11 11 m/s for 500 < t < 1000 sm/s for 500 < t < 1000 s more defects in the lower part of crystal 2
more defects in the lower part of crystal 2
typical of superfluid flow at its critical velocity typical of superfluid flow at its critical velocity
crystal 1 : a single grain boundary
the relaxation at the relaxation at V = 0.6
V = 0.6 m/sm/s stops stops when the cusp
when the cusp disappears disappears
(the grain boundary (the grain boundary moves away,
moves away,
unpinning from the unpinning from the wall somewhere)
wall somewhere)
7.6 7.8 8.0 8.2 8.4
0 500 1000 1500 2000
height h(t) (mm) crystal #1
time (seconds)
Assume 1 grain boundary (thickness e
Assume 1 grain boundary (thickness e ~ a = 0.3 nm~ a = 0.3 nm , width w ~ D = 1cm , width w ~ D = 1cm) ) the critical velocity inside is
the critical velocity inside is
vvccGBGB = (= (DD22/4ew/4ewss)()(CC--LL)V = )V = 1.51.5 (a/e)(D/w)((a/e)(D/w)(CC / /ss)) m/sm/s comparable to 2
comparable to 2 m/sm/s measured by Telschow et al. (1974) on free liquid films of measured by Telschow et al. (1974) on free liquid films of atomic thickness
atomic thickness
1% superfluid density is large !
(Rittner and Reppy 2007: 20% in thin quenched cooled samples !)
1% matter with grain boundaries 1% matter with grain boundaries
~ ~ 1 atomic layer of superfluid matter1 atomic layer of superfluid matter
grain size ~ 100grain size ~ 100 nm nm 3 3 m for 0.03%m for 0.03%
Is this possible ? may be Is this possible ? may be
We used to grow single crystals at We used to grow single crystals at constant P from the superfluid, constant P from the superfluid, butbut
crystals grown at constant V from the crystals grown at constant V from the normal liquid are usually polycrystals normal liquid are usually polycrystals with much more disorder
with much more disorder
a high pressure cell a high pressure cell to grow He crystals at to grow He crystals at
constant V constant V
two cubic cells : 11
two cubic cells : 11 x x 11 11 x 10 mmx 10 mm33
or 11 or 11 x 11 x 11 x 3 mmx 3 mm33
thermal contact via 10 mm thick copper walls thermal contact via 10 mm thick copper walls 2 glass windows (4 mm thick)
2 glass windows (4 mm thick) indium rings
indium rings
stands 65 bar at 300K stands 65 bar at 300K
Straty-Adams pressure gauge (0 to 37 bar) Straty-Adams pressure gauge (0 to 37 bar) connection through a 3 cm long CuNi
connection through a 3 cm long CuNi capillary (0.6 mm ID)
capillary (0.6 mm ID)
at T > 1.8 K from the normal liquid:
growth is dendritic if fast
fast mass injection fast mass injection through the fill line through the fill line in the normal liquid in the normal liquid (here at 1.87 K)
(here at 1.87 K) leads to dendritic leads to dendritic growth
growth
but not slow growth but not slow growth at constant V in a at constant V in a T-gradient
T-gradient
T = 1.87 K T = 1.87 K
11 mm
11 mm
more helium
snowflakes T = 2.58 K T = 2.58 K
slow growth at constant volume
slow growth (
slow growth ( ~3 hours) in a ~3 hours) in a temperature gradient
temperature gradient (T (T
wallswalls< T < T
centercenter) )
the solid is the solid is transparent transparent but but
polycrystalline polycrystalline
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hcp solid hcp solid
liquid liquid
liquid liquid 2.56K 2.56K
hcp solid hcp solid
1.95 K 1.95 K
melting a crystal grown at
constant volume
liquid channels liquid channels appear at the appear at the contact line of contact line of each grain
each grain
boundary with boundary with the windows the windows grain size
grain size ~ ~ m m ripening
ripening
0.04 K 0.04 K
melting a crystal after fast growth from the
superfluid
a : the fast grown solid a : the fast grown solid
is transparent is transparent but polycrystalline but polycrystalline b to f in 11 seconds b to f in 11 seconds
some bulk some bulk liquid
liquid
appears in f appears in f small size crystal grains small size crystal grains
ripening of the solid foam in ripening of the solid foam in
a few seconds at the a few seconds at the melting pressure melting pressure
further melting => 2 crystals + 1 grain boundary
the cusp angle
the cusp angle is non-zerois non-zero => the gain boundary energy => the gain boundary energy GBGBis strictly < 2 is strictly < 2 LSLS
=> partial wetting of the GB by the liquid, the thickness of grain boundaries is
=> partial wetting of the GB by the liquid, the thickness of grain boundaries is microscopic as calculated by Pollet et al. (2007).
microscopic as calculated by Pollet et al. (2007).
complete wetting would imply complete wetting would imply GBGB=2=2LS LS (2 liq-sol interfaces with bulk liquid in (2 liq-sol interfaces with bulk liquid in between)
between)
a 10 mm thick sample
a 10 mm thick sample a 3 mm thick samplea 3 mm thick sample angle 2
angle 2
the contact of the GB with each window is a liquid channel the contact of the GB with each window is a liquid channel
angle measurements => the grain boundary energy
here, the GB is parallel to here, the GB is parallel to the optical axis
the optical axis
a fit with Laplace equation a fit with Laplace equation near the cusp leads to
near the cusp leads to = 14.5 ± 4 ° = 14.5 ± 4 °
GBGB = (1.93 ± 0.04) = (1.93 ± 0.04)
LSLSother crystals:
other crystals:
= 11 ± 3 ° = 11 ± 3 °
= 16 ± 3 ° = 16 ± 3 °
angle 2 angle 2
S.Sasaki et al. PRL 99, 205302 (2007) S.Sasaki et al. PRL 99, 205302 (2007)
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width w ; thickness e width w ; thickness e inversely prop. to the inversely prop. to the depth z (typically depth z (typically 20 20 m at z = 1 cm):m at z = 1 cm):
llcc : capillary length : capillary length
wetting of grain
boundaries near a wall
If If GBGBis large enough, is large enough, more precisely
more precisely ifif + + c c < < /2/2
the liquid wets the contact of the GB with the wall.
the liquid wets the contact of the GB with the wall.
wetting and premelting of grain boundaries: an wetting and premelting of grain boundaries: an important problem in materials science
important problem in materials science
(see for ex. JG Dash Rep. Prog. Phys. 58, 115, 1995) (see for ex. JG Dash Rep. Prog. Phys. 58, 115, 1995) this effect is responsible for the apparent wetting of this effect is responsible for the apparent wetting of GBs observed with fcc crystals by Franck et al.
GBs observed with fcc crystals by Franck et al.
(Edmonton, 1983-5) (Edmonton, 1983-5)
grain 1 grain 1 grain 2 grain 2 liquid
liquid
wallwall
S. Sasaki, F. Caupin, and S. Balibar, PRL 2007 S. Sasaki, F. Caupin, and S. Balibar, PRL 2007
wallwall
grain 1 grain 1 grain 2
grain 2 GBGB
hysteresis of the contact angle
advancing angle : 22 ± 6 ° (copper) 26 ± 7 ° (glass) advancing angle : 22 ± 6 ° (copper) 26 ± 7 ° (glass) receding angle : 55 ± 6 ° (copper) 51 ± 5 ° (glass) receding angle : 55 ± 6 ° (copper) 51 ± 5 ° (glass)
more hysteresis on copper rough walls than on smooth glass walls, more hysteresis on copper rough walls than on smooth glass walls,
as expected from E. Rolley and C. Guthmann (ENS-Paris) PRL 98, 166105 (2007) as expected from E. Rolley and C. Guthmann (ENS-Paris) PRL 98, 166105 (2007)
melting
melting growing growing
the contact line on the window is the contact line on the window is a liquid channel whose width
a liquid channel whose width w w ~ (P-P ~ (P-P
mm) )
-1-1the width w of the triangular the width w of the triangular liquid channel decreases as 1/ z liquid channel decreases as 1/ z
(the inverse of the departure from the equilibrium melting pressure P (the inverse of the departure from the equilibrium melting pressure Pmm)) consistent with the direct measurement but
consistent with the direct measurement but cc is hysteretic is hysteretic the channel should disappear around P
the channel should disappear around Pm m + 10 bar (where 2w + 10 bar (where 2w ~1 nm)~1 nm)
the grain boundary energy
depends on orientation
a stacking fault ? a stacking fault ?
no liquid channel along the no liquid channel along the wall if the GB has a low
wall if the GB has a low
energy (small misorientation)
energy (small misorientation)
two possible interpretations of Sasaki et al. (Science 2006)
the flow could be the flow could be
- either along the GBs (then veither along the GBs (then vcc ~ 1 m/s)~ 1 m/s)
- or at the GB-wall contact (then vor at the GB-wall contact (then vcc ~ 1 cm/s). ~ 1 cm/s).
This would explain why we saw mass flow up to This would explain why we saw mass flow up to 1.1K at least.
1.1K at least.
- to be checked by changing the shape of the cellto be checked by changing the shape of the cell - or by gluing a piece of graphite on the wallor by gluing a piece of graphite on the wall
liquid liquid liquid
liquid solid solid
solid solid
next experiment:
measure T
cinside a grain boundaries
Pollet et al. (PRL 98, 135301, 2007):
Pollet et al. (PRL 98, 135301, 2007):
Tc Tc ~ 0.5 K with three layers~ 0.5 K with three layers 3 times less than the bulk T
3 times less than the bulk T at the solid density (1.5K) at the solid density (1.5K) a possible measurement:
a possible measurement:
squeeze the liquid channels with an electric field squeeze the liquid channels with an electric field
make a height difference make a height difference
measure the mass flow as a function of T measure the mass flow as a function of T
Day and Beamish (Nature 2007): a measurement of the shear modulus of crystals grown at constant V
the shear modulus
the shear modulus increases by ~ 15 % below 100 mKincreases by ~ 15 % below 100 mK dislocation pinning by 3He impurity adsorption ? dislocation pinning by 3He impurity adsorption ?
relation to torsional oscillator experiments ? relation to torsional oscillator experiments ?
less inertia for a stiffer crystal ?? a new theoretical challenge less inertia for a stiffer crystal ?? a new theoretical challenge
shear modulus shear modulus
rotational inertia rotational inertia
similar
similar
anomalies
anomalies
Clark and Chan :
an increase in stiffness ?
=2
=2 (I/G)(I/G)1/21/2
could the decrease in the could the decrease in the period
period be due to an increase be due to an increase in the shear modulus ,
in the shear modulus ,
consequently the quantity G ? consequently the quantity G ?
c/c c/c ~ ~ 30% for NCRIF = 0.4%30% for NCRIF = 0.4%
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conclusion
- solid helium 4 shows many anomalies at low T but their interpretation is not yet solid helium 4 shows many anomalies at low T but their interpretation is not yet clear
clear
see S. Balibar and F. Caupin, « topical review » see S. Balibar and F. Caupin, « topical review » J. Phys. Cond. Mat. 20, 173201 (2008)
J. Phys. Cond. Mat. 20, 173201 (2008)
- superfluidity of solid helium 4 is not established:superfluidity of solid helium 4 is not established:
check phase coherence check phase coherence
- superfluidity of grain boundaries and dislocation cores is predicted but not yet superfluidity of grain boundaries and dislocation cores is predicted but not yet proved experimentally. New original quantum systems 1D or 2D supersolids.
proved experimentally. New original quantum systems 1D or 2D supersolids.
- dynamics of dislocations and grain boundaries in quantum crystals :dynamics of dislocations and grain boundaries in quantum crystals : solid He is stiffer at low T, apparently not superplastic
solid He is stiffer at low T, apparently not superplastic