A NNALES DE L ’I. H. P., SECTION A
S HU N AKAMURA
On an example of phase-space tunneling
Annales de l’I. H. P., section A, tome 63, n
o2 (1995), p. 211-229
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21
On
anexample of phase-space tunneling
Shu NAKAMURA*
Department of Mathematical Sciences, University of Tokyo, 3-8-1, Komaba, Meguro, Tokyo, Japan 153.
Vol. 63, n° 2, 199 Physique theorique
ABSTRACT. - A
typical example
ofphase
spacetunneling,
which isrelated to the
Born-Oppenheimer approximation
and has been studiedby Martinez,
is considered. An upper bound on the width of the resonance,which seems to be
optimal,
isproved.
The main idea is to construct asuitable canonical
transformation,
and then to use the standardAgmon- type exponential
estimate. In order to define resonances, we use a local distortion method.Nous considerons un
exemple
type d’ effet tunnel dansl’espace
des
phases.
Cetexemple
est relie a1’approximation
deBorn-Oppenheimer
et a ete etudie par Martinez. Nous donnons une borne
superieure qui
sembleetre
optimale,
sur lalargeur
des resonances.L’ idee
principale
consiste a construire une transformationcanonique
convenable
puis
d’ utiliser une estimationexponentielle
dutype d’ Agmon.
Pour definir les resonances nous utilisons la methode de distorsion locale.
1. INTRODUCTION
The purpose of this paper is to
study
a class of two-channelSchrodinger
operators as an
example
ofphase-space tunneling phenomena.
In[ 12],
Martinez studied resonances for the
operator:
* Current address: Graduate School of Polymathematics, Nagoya University, Chikusa-ku, Nagoya, Japan 464-01. E.mail: .shu@math.nagoya-u.ac.jp.
Annales de l’Institut Henri Poincaré - Physique théorique - 0246-0211
Vol. 63/95/02/$ 4.00/@ Gauthier-Villars
in the semiclassical limit: 0, where R is an
n-pseudodifferential
operator of 0(1).
Theprincipal symbol
of H(as
an-pseudodifferential operator)
is
given by F" B O xz s ~2 _ . _ i
xy ~, ~ E R,
and the 0-energy
surface is
This consists of two connected components. The first
diagonal
elementsof the
principal symbol
is a harmonicoscillator,
and the spectrum is pure +1 )
=0, 1, 2,...}.
The second element is a Stark Hamiltonian and the spectrum isabsolutely continuous,
and is the whole real line R.Intuitively,
atleast,
eacheigenfunction
of the harmonic oscillator issupported (micro locally)
in a very smallneighborhood
of the0-energy surface {(0, 0)},
whereasgeneralized eigenfunctions
of the StarkHamiltonian is
supported
in a smallneighborhood
=-1+~}.
By
the effect of the lower orderperturbation
theeigenvalue
vanishesgenerically,
and it becomes aquasi-bound
state, or a resonance. Thisphenomenon
may be considered as an interaction between the two0-energy surfaces,
or so-calledtunneling
between them. Thus we can expect,by
ananalogy
of the WKBanalysis,
that theimaginary
part of each resonance(which
isusually
calledwidth),
is 0 with some c > 0as 1i 1
0.Martinez showed that this is true under certain conditions on
R, using FBI-transform,
or morespecifically, Bargman transform,
and the resonancetheory
of Helffer andSjostrand [7].
In this paper, we
mainly
considerspecial
cases where R has the formwhere ~ is the
multiplication
operatorby x, p - (d/ dx),
and a,/3,
1 e C. We will prove an
exponential
bound on the widths of the resonancesusing
certain canonical transform andAgmon-type
estimates. The bound issharper
than the oneby
Martinez[ 12],
and seems to beoptimal, though
wehave not been able to
verify.
Generalization to alarger
class is considered in the last section.l’Institut Henri Poincaré - Physique theorique
In order to state our result
explicitly,
we first introduce a definition of resonances[4], Chapter
8 and referencestherein).
Moreprecise
discussion is
given
in Section 2. We use a class ofahalytic
vectors, definedby
where
cj;
denotes the Fourier transform of ~p:If R satisfies certain
analytic conditions,
inparticular
if R has the form( 1.3),
then the functionis extended
meromorphically
to aneighborhood
of R. We will prove this factusing
local distortion method in Section 2. Apole
of this function is called resonances, in otherwords,
the set of resonances is definedby
R n R is the
eigenvalues
ofH,
and thus resonance is ageneralization
ofeigenvalue. Usually,
resonance is defined as a non-realpole,
but here wedefine the resonances as a superset of the
eigenvalues
for the convenience.THEOREM 1.1. - Let H be
defined by (1.1)
and(1.3).
non-negative integer.
Then resonanceEn (~,)
==(2n
+ + 0(~,2).
Moreover,
for
any 0 65/12,
Remark. - In [ 12], Martinez proved (1.8) for 0
8(3-B/5)/4 5/ 12,
for a
larger
class of R.The
tunneling
estimates forSchrodinger operators
in the semiclassical limit has been studiedextensively. See,
forexample, [ 17], [6], [3],
etc.In these papers,
they
studiedtunneling
effects in theconfiguration
space, i. e. , for the case when the energy surfaces of theprincipal symbol
areseparated spatially. Recently,
thetunneling
effects in momentum space has been studiedby
several authors([ 1 ], [ 12], [ 13], [ 15], [ 16]).
Inparticular,
Martinez studied
operators
of the form( 1.1 ),
which appear in thetheory
of
Born-Oppenheimer approximation
of two-atomic molecules[11], [ 14]).
In order to formulate micro-localexponential estimates,
he used theBargman transform,
which is also called coherent wavepacket expansion
in the
physics
literature[5],
see also[ 16]). By
thisexpansion, L2 (Rd)
is
represented
as asubspace
ofL2-space
on thephase
space:LZ (Rd
xRd).
Vol. 63, n° 2-1995.
This method is
symmetric
inconfiguration
variable x and momentumvariable
ç,
and seemsquite
natural tostudy phase-space tunneling. However,
it is not clear if the estimates obtainedby
this method isoptimal,
since theresults
depend
on the choice of the wavepacket
with which the transform is defined. moreover, the method is not invariant with respect to canonicaltransform,
since theBargman
transform is coherent in x inç.
In this paper, we first use a canonical transform to make our
0-energy
surfaces
separated
in x-variable. The main technical step is theexponential decay
estimate for theeigenfunctions
of the transformed operators, which is a fourth order differentialoperator.
It isproved using
ageneralized Agmon
estimate.The paper is constructed as follows: In Section
2,
we construct the canonical transformexplained above,
and then define severaloperators
necessary in the
proof
of Theorem 1.1. Then the local distortion method is introduced to define resonances. In Section3,
anexponential decay
estimate for the
eigenfunctions
isproved,
and theorem 1.1 isproved
inSection 4. Section 5 is devoted to discussion on the
general
scheme andgeneralizations.
Somesimple
results on-pseudodifferential
operators areexplained
inAppendix.
Acknowledgement. -
The author thanks Professor Andre Martinez forhelpful
discussion and comments.2. PRELIMINARY CONSTRUCTIONS 2.0.
Self-ad j ointness
It is well-known that
p2 -~ x2
andp~ 2014 1 2014 ~
areessentially self-adjoint
onCo (R),
where p = 2014z~ and x denotes themultiplication
operatorby
x. HenceH0 = (p2 + x2 2 _ 0 1 _ B J
isessentially self-adjoint
onCo.
It is easy to see that R isHo-bounded symmetric
operator, hence H =Ho
isself-adjoint
with D(H)
= D(Ho)
if is small.2.1. Canonical transform If we use the canonical transform
then our
principal symbol
is transformed to{ n
-1 - /The
0-energy
surfaces of thediagonal
elements are then{(0, O)}
andPoincaré - Physique théorique
{x
=-1}, respectively,
andthey
areseparated
in the x-variable. Thegenerating
function of the transform is~p+p~/3,
and hence thequantization
is
given by
where .~ is the Fourier transform,
and ç
is theconjugate
variable of x.Then it is easy to see that W is
unitary
andThus we have
where
and
It is easy to see that
Ro
isself-adjoint
on D(p2
+(x
+p2)Z) ~
Dand R’ is
relatively
boundedperturbation
ofHo.
Hence H’ is aself-adjoint operator
with the same domain.2.2.
Approximation system
Here we construct an
operator
on H ~ H =LZ (R)4,
which is agood
approximation
of H’ in order to estimate ImE~ (~).
Let e > 0 be a small constantspecified
later. We chooseji (x)
EC(R).z
=1,
2, so thatM ~
1 andThen we define
JZ
E B(~),
i =1,
2,by
Now let
63, n° 2-1995.
and let J E
B(7~
definedby
J is an
isometry,
i.e., J*J = 1 on ~. Infact,
for
03C61 ~
03C62 ~ H.Then we set K
Kz
on as follows: Let h(.r)
ECo (R)
be anon-negative
function such that h(0)
> 0 andsupp h
C{xl ~~~ 1/2}.
Letk
(x)
E(R)
be anegative
function such thatk0
=sup k (x) -1/4,
and k
(~r) = -~1
+~~
if~x
+11
>~-/2. Ki,o, i
=1,
2, are then definedby
and we let o + As in Subsection 2.1, it is easy to see that z =
1, 2,
areself-adjoint
onSince h
(x)
= 0 onsupp j2
and k(x) =
-1 - x onsupp j1,
we haveHence we obtain
Note
that JZ , ~],
i =1, 2,
are differential operatorssupported
in[-1
+ê/2,
-1 +c].
LEMMA 2.1. - The spectrum
== 1,
2, aregiven
where
I~o
=l~o
+ 0( ~ )
and~’n ( ~ )
=( 2 n
+1 ) ~
+ 0{ ~ 2 ) ;
7(~2) =
== R.
Annales de l’Institut Henri Poincaré - Physique theorique
2.3. Local distortion
In this
subsection,
weexplain
a method of local distortion to defineresonances. This formulation is
formally
very close to the oneby
Hunziker[9],
but is also close to the energy distortion methodby
Babbit and Baslev[2]
in thespirit,
since weessentially
distort the energy of the Stark hamiltonianlocally.
Let x (x)
ECo (R)
be a smooth cut-off function such thatand let M =
sup Ix’ (~r)~.
If () ER, 101 M-1,
then the transformis a
diffeomorphism
inR,
and it induces aunitary
transform inL2 (R):
where
JB (x) = |det (~T03B8/~x)|
= 1 +Bx’ (x)
is the Jacobian. We denoteU03B8 ~ U03B8
inL2 (R) 0 LZ (R) by
the samesymbol Ua (we
will use suchnotations without further
remarks).
It is easy to see thatby
this transformoperators x
and p are transformed as follows:Hence H’
(B)
=UB
H’Ua 1
is ananalytic family
oftype
A in aneighborhood
of 0.Also, Kz (B)
=UB K2 UB 1
is ananalytic family
oftype
A since h(~)
= 0 in aneighborhood
of 0.LEMMA 2.2. - There is 6 > 0 such that H’
(9)
andKz (B)
areanadytic families of
type A inBõ
={z
E8}.
Moreover, thepoint
spectrumof
H’(8)
andKZ (B)
are invariant in B.LEMMA 2.3. -
Ho (B)
=UB Ho UB 1
andK2,o (8)
=Ue K2,o UB 1
areanalytic families of
type A inB6.
Moreover,if 03B4 and
aresufficiently
small.Vol. b3, n° 2-1995.
The
proofs
are standard or easy,possibly except
for(2.20).
In order toshow
(2.20),
we use thefollowing
consequence of theGarding inequality.
LEMMA
2.4.-Z~(~)
>-1/2;~) = -~-1/4~ ~ -1/2.
Then
as an operator
inequality.
Proof. -
If é >-1/2
then we have-1 / 2,
we set e = x to obtainIf x
-1/2,
we set e =-1/2
andThus
(~
++ ~2 > ~ (x)
forx, ~
E R. Then weapply
theGarding
inequality (Appendix,
Theorem5)
toto obtain
(2.20)..
By
Lemma 2.4, we haveif is
sufficiently small,
which wealways
assumeimplicitly.
Since thespectrum
of!7~ ((x
+ +p2
+h (x))
isdiscrete,
and hence isinvariant in
B, (2.26)
andimply (2.20).
We let 03B8 = zA with
sufficiently
small A >0,
which we will fix in the next section. Then the spectrum ofI~2,
o(9)
avoids theorigin.
SinceK2 (8)
is a small
perturbation (8),
we can expect 0 is in the resolvent set ofKZ (B).
Annales de l’Institut Henri Poincaré - Physique theorique
LEMMA 2.5. - There ’ exist c, C > 0 such that
if
issufficiently
small then~ {z
Ec}
C and ’Proof. -
Note that theprincipal symbol
ofK2, o (B)
isIf
I () I
issufficiently small,
thenfor z in a small
neighborhood
of 0by
theargument
above. Henceby
theGarding inequality (or by
the construction ofparametrix),
if and c are
sufficiently
small. On the otherhand,
it is clear thatindependent
of Then(2.28)
followsby
the standardperturbation argument..
Similarly,
H’(B)
is a smallperturbation
ofRo (B)
and thespectrum
isvery close:
LEMMA 2.6. - There exist
En (n)
EC, n
=0, 1, 2,...,
such thatE~ (~,)
==(2n
+1) ~
+ 0(~,2) as ~ j
0,and for
any C > 0,Proof. - By
the standardperturbation argument
as in theproof
ofLemma 2.5
(cf. [10]), (2.33)
holds with ==(2n
+1) ~,
+O (~,).
Here
E~ (~)
is aperturbation
of theeigenvalue (2n
+1) ~x
of the harmonicoscillator. If we note that R has no
diagonal component by
theassumption,
we see
where ~ °
is aneigenfunction
ofHo ( 8 ) .
Hence the 0( ~ ) -term
in theperturbation expansion vanishes,
and we have the desired estimate..Vol. 63, n° 2-1995.
2.4. Resonances
Since the set of
analytic
vectors is invariant under the transform W =eip3 /3,
it suffices to consideranalytic
continuations ofOn the other
hand,
~p E ,.4 is an entire functionby
thePaley-Wiener
theorem.Hence is an x-valued
analytic
function in 03B8 in aneighborhood
of 0.For 03B8 E
R,
we haveBy
theanalyticity,
thisequality
holds forany 03B8
in aneighborhood
of 0.Hence we may set 03B8 = ia in
(2.36)
as in the last subsection.Then g’03C803C6 (z)
is
analytic
in thedomain ~ ~ 7 (H’ (B))
and it haspoles
at theeigenvalues
of H’
(B).
Inparticular,
where C > 0 and
En
are as in Lemma 2.6. Thus we have shown:PROPOSITION 2.7. - There exist
bo
> 0 andEn (li)
EC,
n ==0, 1, 2," ’,
such
that for
any C > 0, the setof resonances for B(C~) - C (
(z~
=0,l,2,...}n~(c~
where(2n -~ 1) b + O (~2).
Prom now on, we will
study
theeigenvalues
andeigenfunctions
ofH’ (8)
in order to prove Theorem 1.1.3. EXPONENTIAL DECAY ESTIMATES
Here we prove that the
eigenfunction decay exponentially
in~Z-1
inclassically forbidden region,
i.e., in an area with which theprojection
ofthe energy surface does not intersect.
We 0, and let
(~) - (2n
+1) ~
+ 0(~2)
be the(n
+1)-th eigenvalue
of.K~ .
Let~~ (x)
be thecorresponding (normalized) eigenfunction.
Annales de l’Institut Poincaré - Physique theorique
It is well-known that for any smooth function p
(x)
onR,
Hence, if a
(~;
x,p)
is a differentialoperator:
a(~;
x;p) _
then
In
particular,
If
p’ (~)
= 0, then theprincipal symbol
of thediagonal
elements arepositive
except = 0. Let us consider under what conditions on p
(~)
itholds. If we solve the
equation: ç2
+(~
+(2)2
= 0in ç
EC,
we haveWe be the least absolute value of the
imaginary part
of the solutionç. Namely, r~ (~) = 1/2 1/4;
=1/2 - ~ + 1/4
if-1/4
a;0; = ~ +1/4 - 1/2
if x > 0. If0 ~ ~p’ (~) ~ ~(a;),
then
We will take a smooth
function p (~r)
so that p(~c) ~
0; p(x)
= 0 in aneighborhood
of0; and - p’ (x) ~
0 isslightly
smallerthan ~ (x).
Sincep
(x)
should beslightly
smaller than 5/12 in a smallneighborhood
of(-1).
Now let 1 -
[-1
+é/2,
-1 + supp[T],
and let ~yo =5/12.
Vol. 63, n° 2-1995.
PROPOSITION 3.1. - There exists C > 0 such that
the
characteristic function
and e’ _(3/4)
c.Proof. -
Motivatedby
the above argument, we set /? e C°°(R)
so that03C1(x)
= 0for x ~
-6 with some 6 > 0;p (x) >
0 for any x eR;
|03C1’ (x)|
~(x)
for x 0;03C1(x)
>~ (y)dy - c/4 for x e (-3/2, 0);
03C1(x)
is constantfor x ~
-2.Let 03C8 = 03C81n.
Then we computeThe
principal symbol of ~’’ - ~ I
isgiven by
and it is
positive
0by
the choice of/) (~).
Note thatFn
=Now let a
(x)
be a smooth function such that: a(x)
issupported
in a smallneighborhood
of0;
supp a c =0}; a (x) ~
0 for any x ER;
anda
(0)
> 0. Then it is easy to seefor any
x, ~
E R with some c > 0. Thenby
theGarding inequality,
we havefor cp E
Thus, by letting ~
= we obtainAnnales de l’Institut Poincaré - Physique theorique
if is
sufficiently
small. Thisimplies,
inparticular,
C.Noting
that
we conclude
(3.7). t!
The same argument holds for H’
(B).
Then we need to use thepositivity
ofinstead of
(3.9). If 101
issufficiently small, however,
we canemploy
thesame
p (x)
to obtain the estimate:for cp E D
(Ho),
as well as(3.11).
We now fix 03B8 " = ia with A > 0 so small that the above " estimate " holds. Then we obtainPROPOSITION 3.2. -
eigenfunction
,I
wi th H’I ~~ _
Then there , exists C > 0 such that
where ~’ ==
(3/4)
c.4. ESTIMATES FOR RESONANCES We first
show
thatEn
=F~
+ 0 for any N > 0.If is sufficiently
small, then r c and.
where ’ C is
independent of
~.Vol. O ’ 2-1995.
Proof. -
Theproof
is standard and weonly explain
the case N = 1, which is in factenough
for our purpose. We setL has no spectrum in a
neighborhood
of 0(if h
issufficiently small),
andit is
easily
shown thatLet a
(:~)
be a smooth function such that a(x)
= 1 on 1 and a(x)
= 0 onThen
by
easycomputations,
But since
[a, Kl~
= 0(~,)
as an operator from D to D(L)*,
the lastterm is
O (~,)
in norm, andclearly
=O (~N)
for z E f.Combined with
(4.3),
thesecompletes
theproof
for N = 1. For thegeneral
case, we use a series of
functions aj (x), j
==1, 2,’ " , N,
with supp aj C(x)
=1}
to carry out the above argumentiteratively..
We set
Then the
right
hand side has asymbol
of 0(~) supported
inI,
and we have COROLLARY 4.2. - Let T be as in Lemma 4.1. Thenis is
sufficiently
small.LEMMA 4.3. - Let C be as in Lemma , 4.1.
If is sufficiently small,
r(B))
and = 1, where ,P (?) is the projection:
Proof. -
As well as(2.13),
we havede Henri Poincaré - Physique theorique
where K
(03B80
=K1 ~ KZ (B).
Henceand
By Corollary 4.2, [’’ -]
is invertible in D(H’)
if issufficiently
smalland z ~
r,
andMoreover,
(4.6) implies
On the other
hand,
theeigenprojection
to theFn-eigenspace
ofK1
isgiven by
and since
KZ (B)
has nospectrum
inf,
Combining
them with the definition of P(B),
we obtainsince
If I
=By
theexponential decay
estimate(Proposition 3.1),
we also haveand hence
Then
(4.14)
and(4.16) imply
63, n° 2-1995.
If 1i is so small that the
right
hand side is less than1,
thenHere we have use the fact that J* is
isometry.
Then
En
is contained in r sinceEn
is theunique eigenvalue
of H’(0)
of the form
(2n
+1) ~
+ 0(~C2)
==Fn
+ 0(h2).
COROLLARY 4.4. - For
En -
Inparticular,
|Im En| I
Proof of Theorem.
1.1. -Let 03C6
be theFn-eigenfunction
of and letthen as in the
proof
0 Lemma 4.3, we havefor any
N,
sinceC~N by (4.11). Combining
this with
(4.15),
we haveif 1i is small. Now we compute the difference of the
eigenvalues En - Fn . Since ~
is anEn-eigenfunction
of H’(0),
On the other
hand,
since ~p is anFn-eigenfunction
ofKl,
we also haveNote that
Tl
=E(H’ (B) Jl - Jl
is a third order differential operator with the coefficientssupported
in suppJi
c[-1 - c/2, -1+6-].
Thenby Propositions
3.1 and3.2,
Combining these,
we concludeBy (4.11),
thisimplies
Annales de l’Institut Poincaré - Physique theorique
5. DISCUSSION
Here we discuss what this
example suggests
us aboutphase-space tunneling.
If we compare our result with the Martinez’result,
our estimateis more than twice as
sharp.
This may suggest that in order to obtainsharp decay
estimation on, e.g.,eigenfunctions,
we have to decide the direction of thedecay
in thephase
space. The direction is notnecessarily linear,
but may be one coordinate of a canonical coordinate system. It seemsimpossible
to obtain a
sharp decay
estimate for the all directions in thephase
spacesimultaneously.
This can be considered as a consequence of theuncertainty principle.
Thus ageneral
scheme of thephase
spacetunneling might
beas follows: In order to estimate
tunneling
effect between two microlocalwells,
i. e. , twodisjoint classically
allowed areas in thephase
space, we first find a canonical coordinate whichseparates
the wells in a maximum way(in
somesense).
Then construct aunitary
transformationcorresponding
thecanonical
change
of coordinate.Finally
we use theAgmon-type
estimatesto prove the
exponential decay
of(generalized) eigenfunctions.
However,situations may be
greatly
varied bothgeometrically (i.e.,
in the behavior of classicalmechanics)
andanalytically (i.e.,
in the choice ofsymbol classes),
and hence it seems
hardly possible
to construct ageneral theory
which isapplicable
to all theproblems
ofphase
spacetunneling phenomena.
At
last,
we sketch an idea of ageneralization
of our theorem in thelower order term R. As is seen from the
proof,
the form of R( 1.3)
isnot
really
relevant. Weonly
need someanalyticity
conditions and upper bounds on thesymbol.
Let 03B4 > 0 and suppose R’ = W RW* has asymbol a(~; ~ ç) == and ~(~;
x,ç)
satisfies thefollowing
conditions: ai~
(~;
x,ç)
isanalytic
inand satisfies
for any
l~,
l >; O. Then theanalytic
continuation(or distortion)
arguments in theproof work,
and R’ is~-bounded.
One technicalproblem
may bethe fact that the
operator R’]
is notnecessarily supported
insupp ji,
even
though
thesymbol
is. But the distribution kerneldecay exponentially
Vol. 63, n° 2-1995.
away from the
support
of thesymbol, by
virtue of theanalyticity
inç.
Werefer
[15]
Section 4 for the detail of this argument.APPENDIX: SYMBOL CALCULUS
We need to use calculus with
symbol
class which includes functions like((x
+ç2)2 + (,2
+1)"B
which is not included in the standardsymbol classes,
e.g.,~’ ((~)N, dx2
+d~z/(~)2).
Here we set the
metric g
onRd
xRd by g
=d~2
+d~2.
Ifm
(x, ç-) E
Coo x$d)
satisfiesand
with
0,
then it is easy to see that mis g
continuous(cf. [8],
Definition18A2),
and c~, gtemperate (cf. [8],
Definition18.5.1 ).
Then thesymbol
class~’ (rrc, g)
is well behaved under the condition(A.1),
and wecan use the
theory
ofWeyl
calculus with thequantization:
In
particular,
satisfies
(A.I).
Thus we can now construct theparametrix
for a e S(mo, g)
such that it is
elliptic
in thefollowing
sense:n
particular, we have
"the Carding
£inequality:
THEOREM A.l. --
Suppose 1 ç)
Eg) satisfies (A.5).
Thenfor
any e > 0 there is C > 0 such thatAnnales de l’Institut Poincaré - Physique theorique
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[4] H. L. CYCON, R. G. FROESE, W. KIRSCH and B. SIMON, Schrödinger Operators, with Applications to Quantum Mechanics and Global Geometry, Springer Verlag, Berlin,
1987.
[5] G. B. FOLLAND, Harmonic Analysis in Phase Space, Princeton Univ, Press, Princeton, 1989.
[6] B. HELFFER and J. SJÖSTRAND, Multiple wells in the semiclassical limit, I., Comm. P.D.E., Vol. 9, 1984, pp. 337-408.
[7] B. HELFFER and J. SJÖSTRAND, Résonances en limite semi-classique, Mem. Soc. Math.,
France, Vol. 24/25, 1986, pp, 1-228.
[8] L. HÖRMANDER, The Analysis of Linear Partial Differential Operators, Vol. III, Springer Verlag, Berlin, 1985.
[9] W. HUNZIKER, Distortion analyticity and molecular resonance curbes, Ann. Inst. H. Poincaré, Vol. 45, 1986, pp. 339-358.
[10] T. KATO, Perturbation Theory for Linear Operators, 2nd ed., Springer Verlag, Berlin, 1976, [11] M. KLEIN, A. MARTINEZ, R. SEILER and X. P. WANG, On the
Born-Oppenbeiraer
expansionfor polyatomic molecules, Commun. Math. Phys., Vol. 143, 1992, pp. 607-639.
[12] A. MARTINEZ, Estimates on complex interactions in phase space, preprint 1992, Université Paris-Nord (To appear in Mathematische Nachrichten).
[13] A. MARTINEZ, Precise exponential estimates in adiabatic theory, preprint 1993, Université
Paris-Nord (To appear in J. Math. Phys.).
[14] A. MARTINEZ, Résonances dans l’approximation de Born-Oppenheimer, I., J. Diff. Eq.,
Vol. 91, 1991, pp. 204-234; II. Commun, Math. Phys., Vol. 135, 1991, pp. 517-530.
[15] S. NAKAMURA, Tunneling estimates in momentum space and scattering, preprint 1993, University of Tokyo (To appear in Spectral and Scattering Theory (ed. M. IKAWA), Marcel Decker, New York, 1994).
[16] S. NAKAMURA, On Martinez’ method of phase space tunneling, preprint, 1994, University
of Tokyo (To appear in Rev. Math. Phys.).
[17] B. SIMON, Semiclassical analysis of low-lying eigenvalues, II. Tunneling, Ann. Math., Vol. 120, 1984, pp. 89-118.
received on May ~7, 19~~.,1
Vol. 63, nO 2-1995.