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(1)U.S. Department. of. Third Conference on CIAP, February 1974. Transportation. BALLOON MEASUREMENTS OF SOLAR FLUXES BETWEEN 1960 Å AND 2300 Å.. P. SIMON Institut d'Aéronomie Spatiale de Belgique Brussels, Belgium. ABSTRACT:. New observational data in the 1960 - 2300 Å wavelength range have been obtained by" spectrometer. Ultraviolet spectra for different zenith angles were recorded means of a balloon-borne with an equivalent slit width of 6 A. Extrapolation to zero air mass leads to extraterrestrial solar fluxes lower than the values measured previously. The present results give an apparent blackbody temperature of the sun on the order of 4700°K at 2000 Å.. INTRODUCTION. pointed. the balloon gondola. arcseconds.. From the point of view of aeronomy,. knowledge. The instrument. the order of 5 arcminutes.. of. the spectral distribution of the ultraviolet solar fluxes reaching the atmosphere is fundamental to determining. is given in Simon (1974).). the photodissociation rates of atmospheric constituents. For instance, in the stratosphere, solar radiation in the. referenced. wavelength. the. The absolute. irradiance. of. matic beam emerging from a McPherson 30-cm-focal length monochromator (model 218). An electroless discharge lamp filled with SiCl4. (emitting silicon. atomic lines in the 1800–2600 Å. range) and a deuterium lamp were used as light sources. The final accuracy of the flight-instrument. wavelength calibration. is estimated to be + 10%.. The resulting instrument. absolute is shown in Figure. | version. is. sensitivity curve of the spec trometer was determined by comparison with a sodium photomultiplier, using a monochro salicylate-coated. INSTRUMENTATION a modified. the spectrometer. International Pyrheliometric. 1956. each flight. The relative. by Ackerman et al. (1971) and by Broadfoot (1972). The data obtained at wavelengths shorter than 1880 Å by Parkinson and Reeves (1969), and confirmed at 1700 Å by recent rocket observations (Ackerman and Simon, 1973; Rottman, 1973) and by satellite experiments (Heath, 1973), show the need for new determinations in the 2000-A atmospheric window. This paper reports new measurements of absolute ultraviolet solar fluxes between 1960 and 2300 Å, by means of a balloon-borne spectrometer obtained integrated into a sun-pointing gondola.. is. of. calibration. thermopile as a transfer standard, mercury lamp was a low-pressure measured at 2537 Å. The spectrometer was directly and absolutely calibrated against this lamp before and after. are those reported. instrument. the. Scale. Using a Reeder. range from 1800 to 2400 Å photodissociates. O2 to form O3. Minor constituents such as N2O, HNO3, and H2O2 are also photodissociated in that wavelength range (see, for example, Nicolet (1972, 1973)); the most recent measurements of solar flux for these constituents. The. to. at the sun to better than 30 alignment accuracy was on (A more detailed description. sensitivity. curve. of. the. 1.. BALLOON SPECTROMETER. -. 10:20. of the. spectrometer. used aboard rockets by Ackerman and Simon (1973). A coarse-ground quartz window, used as a diffuser, was placed in front of the entrance slit to integrate. the. radiation. over. the. whole. solar. -. disk.. 1021. by rotation of a was achieved grating (Bausch and Lomb 35-53-04-020) ruled at 1200 grooves per mm and blazed light was received by a at 2000 Å. The diffracted scanning. $ sºc. source. plane. D.,. 26 X 26 mm. G.. source. |. Spectral. solar-blind photomultiplier (EMR 542 P-09-18) with a RbTe photocathode. The slit width of the spectrometer was equivalent to a triangular slit function with a full. 10-?? 1–1–1–1–1–1–1–1–1–1–1–1–1–1–1 1800 2000 2200 2400 2600 2800 3000 3200 3400 waveLENGTH (A). of 6 Å. The analog output signal to the ground after measurement and. amplification by a solid-state electrometer. The flight instrument was aligned with fine sun sensors which. Figure. 1.. width at half maximum was telemetered. 137. curve of the versus wavelength.. Absolute sensitivity instrument. flight.

(2) SIMON OBSERVATIONS. 15. AND RESULTS. The two flights were carried out on September 23, 1972 and May 16, 1973, at Aire sur l’Adour in France. On the first flight, the balloon (Raven, 3 x 105 m3). T. I. I. I. x -60° z - 39wºrn. 5 *. º-*. of 41.5 km. The main purpose of this flight was the measurement of the stratospheric absorption of the solar radiation (Simon, 1974), so this reached an altitude. 2 of. experiment The. was performed at large solar zenith angles. period extended from 1630 to 1840 Ultraviolet spectra between 1900 and 2300 A. º 1900. observation. GMT.. were obtained 88°.. for zenith angles increasing from 78° to. Figure 2.. to. so measurements were made at relatively angles. Spectra were recorded from 1722 GMT. The corresponding zenith angles. were 54° and 70°. Figure. mine. 2 shows one of the recorded. I. -. ---. –. -T. 10”. AI. --~~2200 Å * ~~. | |-. -: O. -. wn. |. –. +. T. T----_. TTT. ----1960. of extrapolation. 39 km. to zero air mass. |. -. IRRADIANCE. -. OF ALT ITUDE. —. ~~. T. -. AT---. 11. 㺠H | or. ºr. to. bal. -. º #. dur. 1900 A. means of the. 2093 Å. T----- T - - - -. E O >. by. MAY, 16, 1973. T--------__ * - - -. -. l-. Jºe,. obtained. I. MEASURED. `----| T-------. flight from. The classical Langley method was used to deter the optical depth and the extraterrestrial solar. I. I. |. solar spectrum recorded. second. fluxes. Some examples are given in Figure 3.. spectra.. -. l. 2300. loon-borne spectrometer, for a solar zenith angle of 60° and an altitude of 39 km.. smaller solar zenith 1600. the. 2400 A,. fluxes,. solar. Stratospheric ing. On the second flight, the balloon (Winzen, 3 x 105 m3) reached an altitude of 39 km. In this case, the main purpose of the flight was to determine the ultraviolet. l l 2200 2100 wavel ENGTH (A). 2000. -. * -- .. .. .. —. [.. =. |-. 1. 10" O. Figure 3.. |. 1. |. 1. Measured solar wavelengths.. irradiances. 1. |. 2. versus. SEC. X. the. secant. | 38. of the solar. 3. zenith. angle,. at. three.

(3) oxygen. and. ozone,. Z =. I. OPTICAL THICKNESS 39 km. scattering — oxygen ozoneRayleigh experimental values. with different scale. •. constituents,. I. For the first flight, the air masses were calculated using the approximation for large zenith distances given by Swider and Gardner (1967). Since in the wavelength range considered there are two different absorbing. I. SIMON. 2. heights, the contributions at each wavelength of the two absorbers in the air-mass calculation were taken into. The oxygen and ozone column densities were from pressure measurement and from absorp tion data around 3000 Å, respectively. Using the ozone absorption cross-sections measured by Inn and Tanaka (1953) and the oxygen absorption cross-sections pub lished by Ackerman (1971), the optical depth was account.. deduced. tion curve 1900. The solar-flux results of the two flights are shown in Figure 5. The best-fitting curve is reproduced in Figure 6 for comparison with other determinations of. calculated. for an ozone. of. 101.7 molecules/cm2. and. content. of. con. oxygen. tent 1.48 1022 molecules/cm2. The splitting of this curve below 2000 cor responds the lowest and the highest to. Å. solar fluxes in the 1700-2400 Å wavelength interval. The new values are roughly 40% lower than the previous measurements of Ackerman et (1971). They are good agreement with Broadfoot's values for wavelengths. of. values the oxygen cross-section Schumann-Runge band system.. in. al.. the wavelength range from 2400 Å. The full curve was 4 X. model.. in. absorption. pure oxygen-ozone. an. oxygen-ozone. optical thickness (dots) and atmospheric absorp. Experimental in. of the. 2400. x. and those. Figure. a. was also taken into account. Figure 4 shows the good agreement between experimental optical-depth values. ãº. 2100 #5 WAVELENGTH (A). 2000. to. 1900. 4.. 1900. for a pure oxygen-ozone atmosphere between and 2400 Å. The Rayleigh-scattering extinction. calculated. the. |. -. —. -. |-. -. |-. -. "o. -. 10”H. —. -. -. I. -. |-. º. x Ox Ox. MAY. 16, 1973. -. –. -. -. SEPT. 23, 1972. 10. 2000. 2100. 2200. |. |. |. |. l. |. 10 1900. |. 10"E-. |. LL O 2. <ſ. -. T. £. º. T. |-. -. q) un. 'E. FLUX. 10°E-. to.. O. SOLAR. T. -. º. -. –. -. I. I |. I |. |. I. I. E. 10. 14.. 2300. Solar fluxes versus wavelength flights.. at. 5.. waveLENGTH (Å) Figure. one astronomical. 139. unit, deduced from the two balloon.

(4) SIMON 1.. T. |-. |. P. --. º º. Tºt. ---. BROADFOOT ACKERMAN. 6.. Comparison. of ultraviolet. (1970) al. H-. 2100. 2200. -. -. (1971). -. (1972). -. -. SIMON (1973). ROTTMAN (1973) THIS WORK. |. | 2000. et. ACKERMAN. et al. WIDING. -----. |. |. |. 1900. WAVELENGTH Figure. al. (1969). –. 1800. REEVES. 1,500°K. tº 10" 1700. &. PARKINSON. (1961). (1968). 2300. 2400. (A). solar fluxes reported by various experimenters blackbody temperatures are also shown.. from. 1700. to. __. DETWILER BONNET. &. e__. Dr.. —k. _. a. 10". _>1. _`. -. _^. º,. %. H. et. r— V. L^. _` O. R. LL. -. &. 2 É. $. ".. -. 5100°K_^. |. -. X. Jº,. =. --. |. 10". -. I :*. -. SOLAR FLUX. -. § §. I. | #.. |-. # co. |. Comparison. intervals defined. in is. at. are generally used. The agreement. 7. Table. 1.. 1. photodissociation-rate. fairly Table. good. Between the Solar Flux Measurements Reported by Ackerman (1971). Here and the Values Published. Flux Wavelength. 2150. 2150 2198 2222 2247 2273. 1.11. 1.74. 0.97. 2.08. 2.31. 1.11. 2.45. 4.20. 1.71. 5.09. 7.30. 1.43. 12. 9.42. 9.23. 1.06. 1.32 1013. 1.15. 2174. 1.34. 1.59. 21.98. 1.32. 1.10. 2222. 1.22. 1.73. 1.42. 2247. 1.77. 1.80. 1.02. 2273. 1.60. 1.82. 1.14. 22.99. 1.96. 2.26. 1.15. 8.42 1.20. x. 2174. 1.60. x. 2128. 1.38 1.27. x. -. 2128. 2105. 1.44 1.80. x. -. 2105. 2083. 1.53. 7.. -. 2083. 2062. 1.01 1.20. -. 2062. 2041. 1012. 1013. 140. flux. to this work's. -. 2041. 2020. 1.39. (1971). -. 2020. 2000. 1012. Ackerman. -. 1961 1980. This work. -. 1980 2000. -. interval (A). Ratio of Ackerman's. (hu cm-2 secºl). -. than wavelengths.. 1.. 2250 A, but are lower the shorter compare the new Table and Figure values with those published by Ackerman (1971) which longer. in. 2400 A. Fluxes for different. calculations.. for some wavelength.

(5) SIMON R.M. (1968), “Stigmatic spectra of the sun 1800 Å and 2800 A,” Space Res. 8,458.. Bonnet,. between SOLAR FLUx. Broadfoot, A.L. (1972), “The solar 3200 Å,” Astrophys. J. 173, 681. Detwiler,. spectrum. 2100. C.R., D. L. Garrett, J.D. Purcell, and R. (1961), “The intensity distribution in the. Tousey. ---Ackerman tist). solar spectrum,”. ultraviolet. Ann. Geophys.. 17, 9.. r— THis work. 10." 1700. l 1900. I. Figure 7.. l l l 2000 2100 2200 waveLENGTH (A). Comparison. with. l 2.00. SEL. of solar fluxes reported here. values. published. The wavelength. (1971).. | 2300. Donnelly, R.F. and J.H. Pope (1973), “The 1-3000 Å. Solar Flux for a Moderate Level of Solar Activity for Use in Modeling the Ionoshpere and Upper Atmosphere,” NOAA Technical Report ERL 276. by. Ackerman. intervals. are. D.F. (1973), “Space observations of the vari ability of solar irradiance in the near and far ultraviolet,” J. Geophys. Res. 78, 2779.. Heath,. de. fined in Table 1. Since. flux values. the. of Parkinson. and. 25.. Reeves. Inn, E.C.Y. and Y. Tanaka (1973), “Absorption coef ficient of ozone in the ultraviolet and visible regions,” J. Opt. Soc. Amer. 43, 870.. (1969) between 1400 and 1900 Å have recently been confirmed by Ackerman and Simon (1973), Heath (1973), and Rottman (1973), the apparent blackbody temperature of the sun appears to be close to 4550°K at 1900 Å. The present results indicate a decrease of only 150°K from 2000 Å down to 1900 Å. The intensity change from 2080 Å to 1700 Å could be nearly expo nential, as suggested by Donnelly and Pope (1973).. Nicolet,. M. (1972), “Aeronomic chemistry of stratosphere,” Planetary Space Sci. 20, 1671.. the. of aeronomic proc and mesosphere,” Can. J.. Nicolet, M. (1974), “An overview esses in the stratosphere Chem. 52, 1381.. ACKNOWLEDGMENTS. Parkinson,. I would like to express my thanks to Prof. M. Nicolet for his interest in this work, and to Dr. M. Ackerman for his advice in the preparation of the experiment and for the data reduction. I am also indebted to Dr. R. Pastiels, who calibrated the reference source in the IPS 1956 scale, and to Mr. Lippens for his. ments. W.H. in. and. E.M. Reeves (1969), “Measure. the solar. spectrum. 1875 Å with a rocket-borne Phys. 10, 342.. between 1400 and spectrometer,” Solar. Rottman,. G.J. (1973), in R.F. Donnelly and J.H. “The 1-3000 A Solar Flux for a Moderate Level of Solar Activity, for Use in Modeling the Ionoshpere and Upper Atmosphere,” NOAA En vironmental Research Laboratories Technical Re port ERL 276-SEL 25.. computer-programming. Pope,. assistance. This work has been sponsored in part by the CIAP office of the U.S. Department of Transportation through the Office of Naval Research under contract N0014-73-C-0076.. REFERENCES Simon, P. Ackerman, lated. M. to. (1971), “Ultraviolet solar radiation mesospheric. processes,”. re. in Mesopheric. Models and Related Experiments, ed. G. Fiocco, D. Reidel Pub., Dordrecht, Holland, 149.. (1974), “Observation. rayonnement. ultraviolet. sphériques,”. Bull. Acad.. de l'absorption. du. solaire par ballons strato Roy. Belgique, Cl. Sci., in. press.. (1967), “On the and M.E. Gardner of Certain Approximations for the Chap man Function,” AFCRL-67-0468 (Environmental Research Papers, No. 272), Air Force Cambridge Bedford, Mass. Research Laboratories,. Swider,. Ackerman, M., D. Frimout, and R. Pastiels (1971), “New ultraviolet solar flux measurements at 2000 A using a balloon borne instrument,” in New Techniques in Space Astronomy, eds. Labuhn and Lust, D. Reidel Pub., Dordrecht, Holland, 251.. W.,. Jr.. Accuracy. K.G., J.D. Purcell, and G.D. Sandlin (1970), “The UV continuum 1450-2100 Å and the problem of the solar temperature minimum,” Solar. Widing,. Ackerman, M. and P. Simon (1973), “Rocket measure ment of Solar fluxes at 1216 Å, 1450 Å and 1710 A,” Solar Phys. 30, 345.. Phys. 12, 52.. 141.

(6) SIMON DISCUSSION KRUEGER: What is the total absorption sphere above the flight altitude?. Did you attribute the lower problems or to shorter flights?. (UNIDENTIFIED):. of the atmo. to instrument. SIMON:. Calibration techniques. experimental. problem. in. are the most. absolute. vacuum explain. altitude).. Dr. Tohmatsu's. difficult spec. Unfortunately, the difficulties increase in the wavelength range, which ultraviolet would the disagreement between the solar flux measurements. trometry.. SIMON: The optical depth at 2050 Å is 0.2 for the first flight (41.5 kilometers altitude) and 0.3 for the second one (39 kilometers. ultraviolet. values. paper was not available for publication in these Proceedings.. 142.

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