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Preparation of pure Tl2Ba2CuO6+x: the contribution of phase equilibrium studies

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Fig.  I.  Direct  formation  in  the  DTA/TG  apparatus  of Tl 2 Ba 2 CuO 6   showing  the  reduced  weight  losses  (  4%  ) preceding the melting of the sample at 930°C.
Fig. 2 The quasi-binary section TI 2 Ba 2 O 5 -CuO, where (∆) is DTA, (O) single phase by XRD, and (•) two-phase.
Fig. 5. High-temperature X-ray powder diffraction of ortho 2201 in helium: (a) T= 500°C: the (020) and (200) doublet of  ortho  2201;  (b)  T=630°C:  growth  of  tetragonal  2201.
Fig. 7. Enlarged phase diagram at the vicinity. of the 2201 phase.
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