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Access and use of this website and the material on it are subject to the Terms and Conditions set forth at Conductive Terrazzo Flooring
NATIONAL RESEARCH COUNCIL CANADA
DIVISION OF BUILDING RESEARCH
CONDUCTIVE TERRAZZO FLOORING
by P.J. Sereda
bu his
r e p o r t has been prepared f o r information and r e c o r d purposes and i s not t o ber e f e r e n c e d i n any p u b l i c a t i o n ) Report N o .
88
of t h e D i v i s i o n of B u i l d i n g Research Ottawa June1956
PREFACE
Requests f o r i n f o r m a t i o n on e l e c t r i c a l l y conducting f l o o r s f o r h o s p i t a l o p e r a t i n g rooms d i r e c t e d t h e a t t e n t i o n of t h e D i v i s i o n t o t h i s s p e c i a l f l o o r i n g problem and t o t h e need f o r r e s e a r c h . Most of t h e common f l o o r i n g m a t e r i a l s a r e n o t s u f f i c i e n t l y conducting a s normally used, and must be modified through t h e use of a d d i t i v z s such a s carbon b l a c k which a r e i n c o r p o r a t e d d u r i n g manufacture. Conduc- t i v e t e r r a z z o , which must be manufactured i n p l a c e ,
p r e s e n t s s p e c i a l problems and has been t h e s u b j e c t of s p e c i a l s t u d i e s . T h i s r e p o r t which i s one of s e v e r a l i n p r e p a r a t i o n , d e s c r i b e s t h e r e s u l t s o b t a i n e d w i t h c e r t a i n m o d i f i c a t i o n s which were introduced i n t h e manufacture of
conductive t e r r a z z o i n t h e l a b o r a t o r y .
Ottawa,
CONDUCTIVE TERRAZZO FLOOR~AQLA by
P . J . S e r e d a
The r e a s o n s f o r t h e need of s e m i - c o n d u c t i n g f l o o r i n g i n h a z a r d o u s l o c a t i o n s s u c h a s h o s p i t a l o p e r a t i n g rooms have a l r e a d y been d i s c u s s e d ( 1 ) " The p r o p e r t i e s of a number of commercially a v a i l a b l e c o n d u c t i v e f l o o r i n g m a t e r i a l s have
a l s o been p r e s e n t e d ( 2 ) . A s n o t e d i n ( 2 ) , c o n d u c t i v e t e r r a z z o p r e s e n t s s p e c i a l problems and t h e r e f o r e , some r e s e a r c h on
t h i s m a t e r i a l was done i n a n a t t e m p t t o answer t h e f o l l o w i n g q u e s t i o n s : 1. What i s t h e s t a b i l i t y and r e p r o d u c i b i f i t y of t h e e l e c t r i c a l r e s i s t a n c e of c a r b o n t e r r a z z o f l o o r i n g ; 2 . Can a w e t t i n g a g e n t such a s i s o p r o p y l a l c o h o l be used t o d i s p e r s e t h e a c e t y l e n e c a r b o n ' i n t h e cement and w a t e r mix; 3. Would t h e a d d i t i o n of m e t a l f i l i n g s i n t h e s u r f a c e of t h e f l o o r succeed i n d e c r e a s i n g o r e l i m i n a t i n g t h e h i g h c o n t a c t r e s i s t a n c e t o t h e m a t e r i a l ;
4 .
Can t e r r a z z o s e a l e r s be used i n t h e s u r f a c e of c o n d u c t i v e t e r r a g z o f l o o r i n g w i t h o u t i m p a i r i n g i t s c o n d u c t i v i t y ;5.
Are s u p e r a b r a s i o n f u r n a c e b l a c k s s u i t a b l e f o r u s e i n t e r r a z z o f l o o r i n g t o i m p a r t c o n d u c t i v i t y . M a t e r i a l s and Samples T e r r a z z o f l o o r i n g samples m s a s u r i n g by 18 i n c h e s were made from p o r t l a n d cement and K O . 1 and No. 2 w h i t emarble c h i p s i n t h e p r o p o r t i o n s of 1 of cement and 2 of c h i p s . A c e l y t e n e c a r b o n b l a c k s u p p l i e d by Shawinigan Chemicals,
b r a s s f i l i n g s , s u p e r a b r a s i o n f u r n a c e b l a c k d e s i g n a t e d a s P h i l b a c k E s u p p l i e d by P h i l l i p s Chemical Company were t h e a d d i t i v e s used t o i m p a r t e l e c t r i c a l c o n d u c t i v i t y
.
These were p r o p o r t i o n e d by w e i g h t based on t h e weight of cement u s e d . Chemically p u r e i s o p r o p y l a l c o h o l w a s used as aw e t t i n g a g e n t i n t h e s e e x p e r i m e n t s . Chicken w i r e mesh w i t h 1 - i n c h openings was used i n t h e base of t h e s a m p l e s ,
Samples were made by mixing t h e i n g r e d i e n t s i n a Hobbart mixer i n s m a l l b a t c h e s . Each b a t c h made one sample.
When t h e w e t t i n g a g e n t w a s n o t used, t h e b l a c k was mixed w i t h t h e d r y cement and c h i p s , t h e n w a t e r was added and mixed
t h o r o u g h l y . When t h e w e t t i n g a g e n t was u s e d , t h e cement and c h i p s were mixed w i t h one h a l f of t h e t o t a l w a t e r r e q u i r e d . The i s o p r o p y l a l c o h o l was added t o t h e r e m a i n d e r of t h e w a t e r i n c o n c e n t r a t i o n of
1.5
p e r c e n t t h e n t h e b l a c k was mixed i n t o t h i s s o l u t i o n making a p a s t e . T h i s p a s t e was t h e n added t o t h e cement mix and t h e t o t a l mixed f o r n o t more t h a n3 mlnut e s
.
The f i r s t s e r i e s of samples c o n s i s t e d of t h e t o p p i n g mix c o n t a i n i n g 2 p p r c e n t a c e l y t e n e c a r b o n b l a c k t r o w e l l e d t o a t h i c k n e s s of ii i n c h o v e r a $ - i n c h m o r t a r underbed c o n t a i n i n g 3 p e r c e n t a c e t y l e n e b l a c k . The w i r e mesh was used i n t h e underbed, S u b s e q u e n t l y t h e underbed was l e f t o u t and t h e to2p:ng mix a l o n e w a s t r o w e l l e d i n t o forms 9 by
18
i n c h e s by
,,
l n c h deep w i t h t h e w i r e mesh a t t h e bottom of t h e f o r m s . The samples were c o v e r e d w i t h p o l y t h e n e membrane and a l l o w e d t o c u r e f o r two weeks. They were t h e n ground and p o l i s h e d u s i n g wet s t o n e s i n a r o t a r y p o l i s h i n g machine. R e s u l t s and D i s c u s s i o nA l l samples of t e r r a z z o made w i t h 2 p e r c e n t a c e l y t e n e carbon b l a c k showed a remarkable r e p r o d u c i b i l i t y i n e l e c t r i c a l r e s i s t a n c e even though t h e t e c h n i q u e of f a b r i c a t i o n w a s
v a r i e d . T a b l e s I and I1 show t h a t even d r y i n g t h e samples f o r p e r i o d s of 10 d a y s a t 1 3 0 ~ ~ . and 2 2 0 ~ ~ . and d r y i n g i n a room c o n t r o l l e d below 15 p e r c e n t r e l a t i v e h u m i d i t y f o r
s e v e r a l months had l i t t l e e f f e c t on t h e c o n d u c t i u i t y . The low v a l u e of r e s i s t a n c e o b t a i n e d w i t h t h e sample d r i e d slowly i n a room c o n d i t i o n e d below
15
p e r c e n t r e l a t i v e h u m i d i t y may be e x p l a i n e d by t h e f a c t t h a t t h i s sample was n o t washed and some e f f l o r e s c i n g s a l t s may have been brought o u t from t h e sample d u r i n g slow d r y i n g .T a b l e I11 i n d i c a t e s t h a t t h e c o n d u c t i v i t y of t e r r a z z o was n o t changed a p p r e c i a b l y a s t h e c o n c e n t r a t i o n of a c e t y l e n e
b l a c k was d e c r e a s e d t o
li
p e r c e n t .Acetylene c a r b o n b l a c k was found most d i f f i c u l t t o d i s p e r s e i n t h e cement and w a t e r mix of t h e t e r r a z z o because
i t i s n o t w e t t e d by w a t e r and h a s a v e r y low a p p a r e n t d e n s i t y . The N a t i o n a l T e r r a z z o and Mosaic A s s o c i a t i o n recommends
i s o p r o p y l a l c o h o l as a w e t t i n g a g e n t . T h i s a g e n t was t h e r e - f o r e i n v e s t i g a t e d w i t h r e s u l t s a s f o l l o w s . A number of samples of t e r r a z z o c o n t a i n i n g 2 p e r c e n t a c e t y l e n e b l a c k were p r e p a r e d u s i n g i s o p r o p y l a l c o h o l a s w e t t i n g a g e n t . T h i s w e t t i n g a g e n t was e f f e c t i v e i n a i d i n g t h e d i s p e r s i o n of a c e t y l e n e b l a c k i n t h e wet t e r r a z z o mix.
When a c e t y l e n e c a r b o n b l a c k was added t o cement i n t h e t e r r a z z o mix, more w a t e r was r e q u i r e d t o make t h e mix workable t h a n was needed f o r t e r r a z z o w i t h o u t t h e b l a c k . When i s o p r o p y l a l c o h o l was used as a w e t t i n g a g e n t f o r t h e
b l a c k , s t i l l more w a t e r was needed t o make t h e mix workable. 'l'he compressive s t r e n g t h (jf t h e t h r e e mixes of about t h e
same w o r k a b i l i t y was d e t e r m i n e d and t h e r e s u l t s p r e s e n t e d i n F i g . 1. It w i l l be n o t e d t h a t t h e a d d i t i o n c f 2 p e r c e n t a c e t y l e n e b l a c k by weight of cement r e s u l t e d i n a d e c r e a s e i n t h e s t r e n g t h of t h e t e r r a z z o as would be e x p e c t e d from t h e i n c r e a s e d water-to-ct.n;ent r a t i o , The a d d i t i o n of a w e t t i n g a g e n t f u r t h e r debcreased t h e s t r e n g t h p r o p o r t i o n a l t o t h e i n c r e a s e i n t h e water-to-cement r a t i o . S i n c e t h e t h r e e p o i n t s l i e i n 2 s t r a i g h t l i n e it can be r e a s o n e d t h a t
t h e e f f e c t of i s u p r o p , i l alcohol. a s such upon t h e s t r e n g t h of hardened cement was n e g l i g i b l e ,
Samples made w i t h 2 p e r c e n t a c e t y l e n e b l a c k and i s o p r o p y l a l c o h o l a s w e t t , i n g a g e n t gave r e s u l t s of conduc- t i v i t y q u i t e s i m i l a r t o the samples madn w i t h o u t the
w e t t i n g a g e n t ( T a b l e 11). T t k r i l l . be n o ~ e d t h a t sample A-3
was i n t e n t i o n a l l y overmixed f o r I;, m r i n ~ ~ . L e s . 'The e l e c t r i c a l r e s i s t a n c e of t h i s . sample w a s somewhat hi.gher but i t would a p p e a r t h a t t h e mixing time w a s n o t a c r i t i c a l f a c t o r .
When measuring r e s i s t a n c e of t e r r a z z o c o n t a i n i n g
a c e t y l e n e b l a c k by t h s NFPA method
( 3 )
t h e c o n t a c t r e s i s t a n c e between t h e p o s i t i v e e l e c t r o d e and t h e s u r f a c e i s a b o u t t e n t i m e s t h e volurne r e s i s t a n c e of t h e ma.l;e.rial i t s e l f . (The c o n t a c t r e s i s t a n c e of t h e n e g a t i v e e l e c t r o d e i s u s u a l 1 jr small because of t h e p r o c e s s o f e l e c t r o - o s m o s i s a s s o c i a t e d w i t h d - c . p o t e n t i a l s i n such s y s t e m s , ) It h a s been found t h a t b r a s s f i l i n g s i n t h e s u r f a c e of t e r r a z z o c o n t a i n i n g 2 p e r c e n t a c e t y l e n e b l a c k reduced t h e c o n t a c t r e s i s t a n c e of t h e p o s i t i v e e l e c t r o d e t o t h e s u r f a c e . 'This e f f e c t was l e s s pronounced a s t h e c o n c e n t r a t i o n of a c e t y l e n e b l a c k was reduceda able
111). The b r a s s f i l i n g s a r e r e q u i r e d j u s t i n t h e s u r f a c e of t h e t e r r a z z o and a n a t t e m p t was made t os p r i n k l e t h e b r a s s on t h e s u r f a c e w h i l e t h e mix was b e i n g t r o w e l l e d . T h i s was n o t : ; l ~ ~ - c e s s f " u l because most of t h e b r a s s f i l i n g s were removed i n t h e p r o c e s s of g r i n d i n g t h e t e r r a z z o . Some samples were made by i n c o r p o r a t i n g t h e b r a s s f i l i n g s i n t h e mix. A t l e a s t 2 p e r c e n t of brass f i l i n g s by weight of cement was r e q u i r e d t o have a s e a s o n a b l e c o n c e n t r a t i o n i n t h e s u r f a c e which would produce t h e d e s i r e d effect,, T h i s
a d d i t i o n of b r a s s f i l i n g s t o t e r r a z z o c o n t a i n i n g 2 p e r c e n t a c e t y l e n e b l a c k r e s u l t e d i n v a l u e s of r e s i s t a n c e below t h e lower l i m i t . The e f f e c t , ' . o f b r a s s f i l i n g s was l e s s pronounced a s t h e c o n c e n t r a t i o n of S l a c k was d e c r e a s e d whereas t h e
volume r e s i s t a n c e of t h e s a l ~ l p l e s i n c r e a s e d and became more dependent upon t h e m o i s t u r e c o n t e n t , T e r r a z z o c o n t a i n i f i g 1 p e r c e n t a c e t y l e n e b l a c k and 2 p e r c e n t b r a s s f i l i n g s
might be s u i t a b l e but t h e advantage o v e r t e r r a z z o c o n t a i n i n g 2 p e r c e n t a c e t y l e n e b l a c k a l o n e i s n o t e v i d e n t from t h e r e s u l t s . S i x p r o p r i e t a r y t e r r a z z o s e a l e r s were a p p l i e d on one h a l f of t h e samples of t e r r a z z o c o n t a i n i n g 2 p e r c e n t a c e t y l e n e b l a c k t o observe t h e i r e f f e c t upon e l e c t r i c a l r e s i s t a n c e . These s e a l e r s p e n e t r a t e d i n t o t h e t e r r a z z o and d i d n o t form t h i c k c o a t i n g s on t h e s u r f a c e . In a l l c a s e s t h e s e s e a l e r s caused o n l y a s l i g h t d e c r e a s e i n t h e r e s i s t a n c e of t h e c o n d u c t i v e t e r r a z z o f l o o r i n g . T h i s was c h a r a c t e r i s t i c of t h e s e m a t e r i a l s under a l l c o n d i t i o n s of t e s t i n c l u d i n g d r y i n g t o 220°F. Acetylene c a r b o n b l a c k h a s s o f a r been t h e o n l y c o n d u c t i v e i n g r e d i e n t used i n t e r r a z z o f l o o r s . T h e r e f o r e samples of t e r r a z z o were made c o n t a i n i n g one s p e c i f i c t y p e of t h e s u p e r a b r a s i o n f u r n a c e b l a c k s made by P h i l l i p s Chemical Company. It was found t h a t t h i s b l a c k was s l i g h t l y w e t t a b l e by w a t e r and c o u l d be d i s p e r s e d i n t h e w a t e r and cement mix w i t h o u t much d i f f i c u l t y . The e l e c t r i c a l r e s i s t a n c e s of t h e s e
samples a r e g i v e n i n T a b l e
IV.
It i s a p p a r e n t t h a t t h e f u r n a c e b l a c k s e r v e d a s a n e f f e c t i v e c o n d u c t i n g a g e n t . The compressive s t r e n g t h of one b a t c h of t e r r a z z o c o n t a i n i n g t h e f u r n a c e b l a c k was checked and t h e r e s u l t i n d i c a t e d a d e c r e a s e of s t r e n g t h compared t o t e r r a z z o made w i t h a c e t y l e n e b l a c k . T h i s s h o u l d be checked a g a i n s i n c e t h i s r e s u l t i s based ono n l y one b a t c h .
Swnmary and Conc l u s i o n s
1. S u c c e s s i v e b a t c h e s of t e r r a z z o w i t h 2 p e r c e n t a c e t y l e n e carbon b l a c k from which samples were made, showed remarkable r e p r o d u c i b i l i t y of e l e c t r i c a l r e s i s t a n c e a s measured by
NFPA method. The r e s i s t a n c e of t h e s e samples remained below 1 megohm even a f t e r d r y i n g i n t h e oven a t 2 2 0 " ~ . ; 2 . I s o p r o p y l a l c o h o l i n c c n c e n t r a t i o n of 1* p e r c e n t i n w a t e r
was found s u i t a b l e a s a w e t t i n g a g e n t f o r a c e t y l e n e carbon b l a c k . T h i s w e t t i n g a g e n t as s u c h d i d n o t a f f e c t t h e
s t r e n g t h of t h e hardened cement. It d i d , however, r e q u i r e more w a t e r t o be used i n t h e mix r e s u l t i n g i n a d e c r e a s e
i n compressive s t r e n g t h of t h e sample;
3 . B r a s s f i l i n g s i n t h e s u r f a c e of t e r r a z ~ o c o n t a i n i n g 2 p e r
c e n t a c e t y l e n e b l a c k d i d reduce t h e c o n t a c t r e s i s t a n c e between t h e e l e c t r o d e and t e r r a z z o s u r f a c e . T e r r a z z o f l o o r i n g h a v i n g a r e s i s t a n c e (NFPA method) l e s s t h a n 10,000 ohms can be o b t a i n e d i n t h i s way. T h i s e f f e c t d e c r e a s e d a s t h e c o n c e n t r a t i o n of b l a c k i n t e r r a z z o was d e c r e a s e d . I n a d d i t i o n when t h e c o n c e n t r a t i o n of a c e t y l e n e
black was decreased i n t h e samples c o n t a i n i n g b r a s s f i l i n g s , t h e r e s i s t a n c e became l e s s s t a b l e . These r e s u l t s could not j u s t i f y t h e use of b r a s s f i l i n g s a l o n g w i t h a c e t y l e n e
carbon black i n t e r r a z z o f l o o r i n g u n l e s s a f l o o r w i t h very low r e s i s t a n c e was d e s i r a b l e ;
4. Terrazzo s e a l e r s of t h e p e n e t r a t i n g type were found t o have no i n j u r i o u s e f f e c t upon t h e e l e c t r i c a l r e s i s t a n c e
of conductive t e r r a z z o f l o o r i n g samples;
5.
I n d i c a t i o n s a r e t h a t super a b r a s i o n f u r n a c e b l a c k s can be used as t h e conductive i n g r e d i e n t i n t e r r a z z o . However, t h e r e i s some evidence t h a t t h e one type t e s t e d had some d e l e t e r i o u s e f f e c t upon t h e s t r e n g t h of t h e hardened cement.A number of t e r r a z z o f l o o r s , s p e c i f i e d t o c o n t a i n 2 p e r c e n t a c e t y l e n e b l a c k , when i n s t a l l e d i n h o s p i t a l s d i d n o t meet t h e requirements of c o n d u c t i v i t y
.
Present l a b o r a t o r y r e s u l t s i n d i c a t e t h a t t h e c o n d u c t i v i t y of t e r r a z z o is s a t i s - f a c t o r y over a r a t h e r wide range of eoncentsat ions of a c e t y l e n e black. It a p p e a r s , t h e r e f o r e , t h a t t h e d i s p e r s i n g and propor- t i o n i n g of a c e t y l e n e black i n t e r r a z z o on t h e jobs wasp a r t i c u l a r l y poor and t h a t t h e r e were a r e a s of f l o o r i n g c o n t a i n i n g l e s s t h a n 1 p e r c e n t a c e t y l e n e black.
It i s recommended, t h e r e f o r e , t h a t i s o p r o p y l a l c o h o l be used as a w e t t i n g agent t o d i s p e r s e a c e t y l e n e b l a c k i n t h e t e r r a z z o mix and t h a t a l l i n g r e d i e n t s be c a r e f u l l y proportioned and mixed thoroughly. The m i x should be of
such c o n s i s t e n c y t h a t i t could be t r o w e l l e d on t o t h e s u b f l o o r .
References
1. Legget, R.F. and P.J. Seseda. Conductive f l o o r s f o r s a f e t y i n h o s p i t a l s . J o u r n a l , Royal A r c h i t e c t u r a l I n s t i t u t e of Canada, v o l , 31, no. 11, November 1954. ( ~ e p r i n t e d a s NRC 34671,
2 . Sereda, P. J
.
Propert i e a of commercial conductive f l o o r i n g s f o r h o s p i t a l o p e r a t i n g rooms. National Research Council, D i v i s i o n of Building Research. A p r i l1956.
3. Recommended s a f e s a c t i c e f o r h o s p i t a l o p e r a t i n g rooms. N.F.P.A. No.
5
g
of t h e National F i r e P r o t e c t i o n A s s o c i a t i o n , Boston, 40p.TABLE I
E l e c t r i c a l R e s i s t a n c e of T e r r a z z o C o n t a i n i n g 2% Acetylene Carbon Black by Weight of Cement ( N O w e t t i n g a g e n t )
*
T h i s h i g h r e s i s t a n c e d e c r e a s e d t o i n i t i a l low v a l u e i n v e r y few minutes a f t e r t h e sample was brought i n t o a room c o n d i t i o n e d t o 5076 R.H. Sample No. 1 23
10 11**
T h i s v a l u e was o b t a i n e d a f t e r sample was l e f t t o d r y f o r two months i n a room c o n d i t i o n e d below 15% R . H .R e s i s t a n c e ( t h o u s a n d s of ohms) - C o n d i t i o n e r t o
5G$
R . H ,175
190
130 200 190 Washed w i t h = € e r g e n t s o l u t i o n e v e r y working d a y f o r3
months 6055
65
~r iz-Xmy' f o r t e n days 440*
380
30**
.
TABLE I1
E l e c t r i c a l R e s i s t a n c e of T e r r a z z o Containing
25
Acetylene Carbon Black Dispersed by Means of I s o p r o p y l Alcohol*
A - 3 was mixed f o r 1 5 minutes a f t e r t h e carbon p a s t e was added. Other samples were mixed f o r 3 minutes a s recommended i n t h e s p e c i f i c a t i o n of N a t i o n a l Terrazzo and Mosaic A s s o c i a t i o n .Sample No. A - 1 A - 2 *A-3 B-1
**
T h i s h i g h v a l u e decreased t o 150 a f t e r t h e sample had been i n t h e room c o n d i t i o n e d a t 50% R . H . f o r 20 minutes. R e s i s t a n c e ( t h o u s a n d s of ohms) Dried i n oven a t 2 2 0 ' ~ . f o r 10 days 300 3,000"*
Conditioned t o50%
R . H . 100 110 250 150 Washed w i t h d e t e r g e n t s o l u t i o n e v e r y working day f o r 1 month 80 70 90TABLE 111
E l e c t r i c a l R e s i s t a n c e of Terrazzo Containing Various C o n c e n t r a t i o n s of Acetylene Carbon and Brass F i l i n g s
Brass f i l i n g s $ by w t . of cement i n s u r f a c e I 1 I I I1 1 1 11 0 i n s u r f a c e It I I 11 1 2 Sample No. 4 5 A - 4 A-5 A -6 A - 8 A - 7 A-ll A-12 A - 1 3 A - 1 4 B-2 B-3 1 R e s i s t a n c e ( t h o u s a n d s of ohms) $ Carbon by w t . of cement 2 2 1s 1
4
O O 1% 1* 13
1 1 Conditioned t o50s
R.H. 13 7 10 45 330 2,000 1,500 4 25 35 300 350 325 , Dried a t 220°F. 47 2505
000 5,000 5,000 8 350 5 000 5,000 5 000TABLE
IV
E l e c t r i c a l R e s i s t a n c e of T e r r a z z o C o n t a i n i n g V a r i o u s C o n c e n t r a t i o n s of Super Abrasion Furnace B l a c k s and B r a s s F i l i n g s Sample No. C - 1 C - 2c-3
C - 4 R e s i s t a n c e ( t h o u s a n d s of ohms) Conditioned t o 50% R . H . 147 190 200 120 Cornposit i o n $ b l a c k 215
1 2 Dried a t 220°F. 500 900 5,000 710 $ b r a s s 0 0 2 0 Notes W e t t i n g a g e n t W e t t i n g a g e n t W e t t i n g a g e n t N o w e t t i n g a g e n tWATER T O CEMENT RATIO LEGEND;