Tuning the size of a redox-active tetrathiafulvalene-based self-assembled ring

This ability to electrochemically detect a guest cation is assigned to the conjunction of a suitable location of the binding site related to the redox unit, associated to a

Perylenediimide (PDI)-based self-assembled monolayers (SAMs) have been studied by using quartz crystal microbalance, X-ray photoelectron spectroscopy, cyclic voltammetry, and

Preliminary electro- chemical properties have been investigated by cyclic voltammetry (CV), which confirm the ability of such assemblies to generate a reversible redox behavior,

Variations of these two parameters (i.e. FWHM and i Peak 1 /i Peak 2 ) as a function of surface coverage provide results (when redox centers present two successive redox

This corresponds to a cavity size which is roughly double compared to the parent square built from a 4,4 0 -bipyridine bridging ligand, 13 which makes this system one of the

panoply of reducible or oxidable discrete cavities which differ by the structure or by the function. From this point of view, and as shown through various examples in

With the respect of drastic experimental conditions, the adsorp- tion reaction of redox-responsive TEMPO SAMs can be described by the Langmuir isotherm, even if the Frumkin model

3 In the course of our studies related to the designing of new electron-rich receptors incorporating the tetrathiafulvalene unit, 4 we recently investigated the preparation of