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Electrochemical Mechanism of TiMnSn4 as Anode Material for Li-ion Batteries

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50 ICAME 2017 Talk C-15 Monday Afternoon Session 1B, 15:00 Speaker: Pierre-Emmanuel Lippens

T03: Materials Science and Industrial Applications

Electrochemical Mechanism of TiMnSn

4

as Anode Material for Li-ion Batteries

Lippens P.E.1, Jumas J.C.1, Olivier-Fourcade J.1, Sougrati M.T.1, Chamas M.2, Mahmoud A.3

1 - Institut Charles Gerhardt, UMR 5253 CNRS, Université de Montpellier, Place Eugène Bataillon, F-34095 Montpellier cedex 5 France

2 - School of Chemistry and Chemical Technology, Southwest Petroleum University, Chengdu 610500, China 3 - LCIS/GREENMAT, Institut de Chimie, Université de Liège, Allée de la Chimie, B-4000 Liège, Belgium

lippens@univ-montp2.fr

Li-ion batteries are widely used in portable electronic devices, electric vehicles or energy storage sys-tems for intermittent energy sources, due to their high energy density, light weight and long cycle life. However, the performances must be continuously improved, which requires the development of new HOHFWURGHPDWHULDOV&DUERQLVFRPPHUFLDOO\XVHGIRUWKHDQRGHEXWLWVVSHFL¿FFDSDFLW\LVOLPLWHGWR 372 mAh g-1GXHWRWKHHOHFWURFKHPLFDOLQVHUWLRQPHFKDQLVPLQYROYLQJRQO\/LSHU&,QRUGHUWR

LQFUHDVHWKHVSHFL¿FFDSDFLW\6QZDVFRQVLGHUHGDVHOHFWURFKHPLFDOO\DFWLYHHOHPHQWDOWKRXJKLWLVDERXW ten times heavier than C. This is due to the alloying/dealloying mechanism with up to 4.4 Li per Sn, SURYLGLQJDWKHRUHWLFDOFDSDFLW\RIP$KJ-1+RZHYHUWKH6Qļ/L

4.4Sn reversible transformations

are associated with large volume variations responsible for capacity fading.

Tin intermetallic compounds of the form MSn[, where M is a transition metal, were proposed to over-FRPHWKLVSUREOHP7KH¿UVWOLWKLDWLRQWUDQVIRUPVWKHSULVWLQHPDWHULDOLQWR/L7Sn2/M nanocomposites

ZKHUHWKH0QDQRSDUWLFOHVDUHH[SHFWHGWREXIIHUWKHYROXPHYDULDWLRQV>@+RZHYHUWKHGHOLWKLDWLRQ SURFHVVLVPRUHFRPSOH[LQYROYLQJDSRVVLEOHEDFNUHDFWLRQRI0ZLWK6QZKLFKFRXOGSOD\DFUXFLDO UROHLQWKHF\FOLQJVWDELOLW\6XFKUHDFWLRQZDVREVHUYHGIRU1L3Sn4 [2] and MnSn2 [3] but not for FeSn2 [4]. In addition, TiSn[LQWHUPHWDOOLFVVKRZYHU\SRRUHOHFWURFKHPLFDODFWLYLW\>@

The present work concerns the tin based ternary phase TiMnSn4 as new anode material for Li-ion bat-teries. This compound is of particular interest because it contains two different transition metals that are H[SHFWHGWRUHDFWGLIIHUHQWO\ZLWK6QGXULQJGHOLWKLDWLRQLIZHFRQVLGHUWKHSUHYLRXVUHVXOWVREWDLQHG for MnSn[ and TiSn[. TiMnSn4 was obtained by mechanosynthesis to optimize the microstructure and FKDUDFWHUL]HGE\GLIIHUHQWH[SHULPHQWDOWRROVDQG')7 GHQVLW\IXQFWLRQDOWKHRU\ FDOFXODWLRQV:HSUR-pose an analysis of the reaction mechanism based on operando X-ray diffraction and Sn Mössbauer spectroscopy combined with a DFT interpretation of the electrochemical potential curve.

References 1) 0&KDPDV076RXJUDWL&5HLEHO3(/LSSHQV&KHP0DWHU    ..'(KLQRQ61DLOOH5'HGU\YqUH3(/LSSHQV-&-XPDV'*RQEHDX&KHP0DWHU     $0DKPRXG0&KDPDV-&-XPDV%3KLOLSSH5'HGU\YqUH'*RQEHDX,6DDGRXQH 3(/LSSHQV-3RZHU6RXUFHV    0&KDPDV3(/LSSHQV-&-XPDV.%RXNHUPD5'HGU\YqUH'*RQEHDX-+DVVRXQ 63DQHUR%6FURVDWL-3RZHU6RXUFHV  

 A. Ladam, L. Aldon, P.E. Lippens, J. Olivier-Fourcade, J.C. Jumas, C. Cenac-Morthe, +\SHU¿QH,QWHUDFW  .

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