Thermal and light-induced spin crossover in cobalt(II) imine complexes and in the polymeric network [Fe(bbtr)3](ClO4)2

A particular attention is drawn on the light-induced excited spin-state trapping effect, the most studied phenomenon, by discussing the recent developments in terms of description

The result was a broad single line (not Lorentzian) of 2.5 mm/s half width for both tempera- tures. It yielded a single line of about the same line width and form. The spectra

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As a consequence, both solvatomorphs displayed thermal Spin Crossover at high temperature (T 1/2 = 320-340 K) nevertheless the one for 1 presented an abrupt

Thermal transition curves in neat iron(II) spin-crossover compounds are thus invariable much steeper than in diluted mixed crystals, and the high-spin“ low-spin relaxation following

By the photoexcita- tion with the blue (or green) light, the LIESST process takes place and after certain time the crystal converts to a 100% metastable high-spin state [7]..

For a quantitative evaluation of these data, it is preferable to plot the high-spin fraction, γ HS , as a function of the product of irradiation time and intensity, It (mJ/mm 2 ),

With this purpose in mind we have focused our work on the analysis of the structural evolution of two different systems during the HS⟶LS relaxation: The Hofmann