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Efflorescence on the exterior surface of masonry walls: a review of the literature
Ser
THI.
392
no. 8
c . 2 EFFLORESCENCE
ON
THX EXTERIORSURFACE
OFMASONRY IVALLS
( A review of t h e literature) by
Abstract
The t w o
general
conditions necessaryto
produce efflorescence in masonry w a l l s a r e
( a ) presence of s o l u b l e salts in the w a l l mate- rials and ( b ) moisture to c a r r y these s a l t s ts- wards a r onto &he s u r f a c e of t h e wall.
No s i m p l e method, capable o f general appli-
c a t i o n ,
h a s been devised to l i m i t the solublesalt
c o n t e n tin
masonry materials. Hardly any masonry material is exempt f r o m t h e possibilityof
c o n t a i n i n gsufficient
soluble s a l t s tocon-
t r i b u t e to t h e development of noticeable ef-
florescence if moisture
should
p e n e t r a t e t h ew a l l .
Moisture p e n e t r a t i o n of t h e w a l l , and with it, efflorescence, nay be almost completely pre-vented by p r o p e r d e s i g n , construction, and main-
tenance of the building-
7 11.' 3 . 3 ~ ; -
-
EFFLORESCZ$iCE
OM
THS EXTZRIOR SURFACE OF &tASQNRY =-- - ..-.
WALLSmen moisture g a i n s a c c e s s to masonry walls, the water-soluble s a l t s present in the masonry m a t e r i a l s a r e taken
i n t o solution, a n d as soon as t h e weather becomes favourable
f o r evaporation of this accumulated moisture, t h e s a l t s a r e c a r r i e d in solution t o w a r d the outer f a c e of t h e wall. The concentration of the salts in solution increase w i t h c o n t i n u e d
e v a p o r a t i o n ,
until
the s a l t s f i n a l l y crystallize out, forminga
whitish
d e p o s i t which is termedefflorescence.
The p o i n t at which c r y s t a l l i z a t i o n o c c u r s will depend l a r g e l y on the c a p i l l a r y properties of the m a t e r i a l s ,
It
may be in a l a y e r just behind the surface, o r directly on t h e s u r - face.In
t h e former c a s e , the crystallization may l e a d to d i s r u p t i o n and s p a l l i n s of the surface l a y e r ; in the latter case, i t p r o v i d e s disfigurement.While
efflorescence is most common in the e a r l y s p r i n g when walls s a t u r a t e d by m e l t i n ? snow or l a t e w i n t e r r a i n s are d r y i n g out, it may occur a t any time o f t h e y e a r . It may a p p e a r q u i t e g e n e r a l l y over a wallar
b e c o n f i n e d to certain small areas.The two g e n e r a l c o n d i t i o n s necessary t o produce ef- florescence, in a l l i n s t a n c e s , are:
a. Soluble s a l t s present in t h e w a l l materials. b . Moisture to c a r r y these s a l t s towards o r o n t o
the wall s u r f a c e . 2 . Nature of t h e Soluble S a l t s
Some o f t h e s a l t s frequently found in efflorescence are calcium sulphate (gypsum), magnesium sulphate (epsom s a l t s ) ,
sodium c h l o r i d e (table salt), sodium sulphate and potassium
s u l p h a t e . These a r e a l l
soluble
i n
w a t e r , though calcium sul- phate is considerably less soluble than t h e others a n d is l e s slikely
on
thisaccount
toform a
majorconstituent
of e f f l o - r e s c e n c e ,In
cases where seriousfailure
o f brickwork by salGa c t i o n
have
been r e p o r t e d at t h eBritish
Building ResearchS t a t i o n , it h a s n e a r l y always been found that magnesium s u l p h a t e
w a s t h e destructive agent.
The p r e s e n c e of n i t r a t e s and chlorides is usually an i n d i c a t i o n of contamination
from
some external source, such a s ground-wateror
material stored in contact with the a f f e c t e d masonry.3 .
Origin of t h e S a l t s-
H a r d l y a n y masonry material is exempt from t h e pos-
s i b i l i t y of c o n t a i n i r ~ g sufficient soluble s a l t s to contribute to the development of noticeable efflorescence
if
moisturep e n e t r a t e s the wall. The
usual
sources of soluble s a l t s a r e :( a ) F a c i n g
or
back-up m a t e r i a l , such as b u i l d i n g l i m e s t o n e s , b r i c k s , hollow tile, c o n c r e t e units,or monolithic concrete.
( $ 1
Mortars and p l a s t e r s .In
this case, t h e s a l t smay'be due to one
or more
of the ingredients.Portland
cements, certain sands,-and certain limes containsoluble salts;
and in some in-s t a n c e s the mixing water
for
t h e mortar o rplaster may contain
soluble
salts.( c ) Ground-water or some other e x t e r n a l source,
S a l t s a r e introduced into t h e cement f r o m b o t h
the
r a w materials and the coal a s h . Some o f t h i s salt c o n t e n t may b e volatilized in the k i l n and c a r r i e d away in t h e dust, t h eamount so removed i n c r e a s i n g with harder burning.
S a l t s p r e s e n t in the bricks may o r i . g i n a l l y have been present in t h e c l a y
or
tempering water. They may have been produced during the manufacturing process by t h e decomposition of compounds presentin
t h e c l a yor
by t h e a c t i o n of s u l p h u r gases in t h e kiln. The c o n t e n tof
soluble s a l t s in bricks v a r i e s g r e a t l y , although t h e actual q u a n t i t y of soluble s a l t sis very m a l l , even in bricks which may produce efflorescence.
Foreover, the effect of soluble
salt
content in building mate-rials
is so intimately bound up with t h e capillary propertiesand pore structures that a material should n o t be condemned on its salt c o n t e n t a l o n e , with t h e possible exception of the
Even if the f a c i n g b r i c k is carefully chosen, s a l t s c o n t a i n e d in t h e back-up units
or
in t h e mortar used f o r joint-i n g a n d pointing may b e transferred t o facings by t h e movement
of water in t h e walls. T h i s m i g h t l e a d a c a s u a l observer to t h e e r r o n e o u s conclusion that the facing bricks were d i r e c t l y responsible, whereas they may a c t u a l l y
have
been almost f r e efrom s o l u b l e
s a l t s
o r i g i n a l l y .In
t h i s connection, it is interesting to note t h a t t e s t s at t h e U.S. aureau of Standards on55
types o f f a c e b r i c kfrom
a s many d i f f e r e n t manufacturers in various p a r t s of t h e United S t a t e s were examined f o r s o l u b l e s a l t s , and t h e majority were found to c o n t a i n less than 0,05 p e r cent of soluble s u l - phuric a n h y d r i d e , a n amount insufficient t o cause efflorescence under c o n d i t i o n s favourable f o r such. It would seem t h e r e f o r e , that t h e face-brick manufacturers have reduced the tendency oft h e i r p r o d u c t to e f f l o r e s c e to a c o n s i d e r a b l e e x t e n t .
It
is
claimed by t h e Structural Clay P r o d u c t sInsti-
tute t h a t p r o b a b l y more than 90 per c e n t of t h e o u t p u t ofstructural clay products in this country w i l l nut tend to ef- floresce. They p o i n t o u t , however, that second-hand brick,' because of its uncertain o r i g i n and p r e v i o u s c o n t a c t w i t h
m o r t a r and p l a s t e r , may f r e q u e n t l y be a source of efflorescence.
4
Methods of Noisture P e n e t r a t i o nMoisture may come in c o n t a c t w i t h walls f r o m d r i v i n g r a i n s , melting snow, or ground-water, and may p e n e t r a t e the walls as a result of the following:
(a)
Insufficient a t t e n t i o n of t h e architect to p r e -c a u t i o n a r y d e t a i l
i n
d e s i g n i n g .( b j Poor workmanship and materials used during the
construction period.
[ c ) Improper maintenance or o p e r a t i o n of the corn- pleted b u i l d i n g .
The U . S . Bureau of S t a n d a r d s has made a d e t a i l e d s t u d y of 250 cases of efflorescence and w a l l d i s i n t e g r a t i o n , and concluded that a l l b u t ohe
or
two of the cases c o u l d have b e e n prevented by either proper-design, construction, ormaintenance.
In
Part 7 1of
t h i s paper, some of t h e g e n e r a l l yre-
c o g n i z e d methods o f preventing moisture penetration into t h e walls will b e d i s c u s s e d .
It
should be n o t e d a tthis
p o f n t , however,that
In
t h e ease of
a
new buPlding, a uniform e o a t f ng of deposf t e d s a l t s may appear,even
whenall
reasanable pracautfons have beentaken. Thf s c o n d i t f
on
is the r e s u l t of the v e r y l a r g e quantf ti e sof water used
in
t h econstruction
procezs,After
t h e wallshave
had an opportunfty to dry thoroughly, a f h a l cleaning or some- times n f e w raFns w P l l wash away the efflorescence a n d it
se Edom appears agaf
n,
The
.vfew fs held by some that new brickwork is partl- c u l a r l y liable to damp p e n e t r a t i o n troubles, and t h a t the n a m ~ l progress of weathering dfmfnfshes t h e permeability of the w a l L by a process of s5ltfng up p o r e s by d P r t and v e g e t a t f o n ,Why Eff
loreacence
Should be PreventedEfflorescence should be prevented because of I t s un- sfghtliness and because crystallization
i n
a layer gust behfndt h e wall s u r f a c e may cause the smface Eager of t h e masomy
to
spall,Another, and even more aarfous a s p e c t of t h e sftuatlon,
is
t h a t efflorescence, e x c e p tPn
t h e case ofa
new bufldlng adnoted above, 1s a symptom of m o i s t w e p e n e t r a t i o n into ths WELS,
Wet walls r e s u l t Xn decreased fnsulatfon value of the wall and
In damp f n t e r i o r s , and may e ~ e n t a a l l y lead t o partfal
or
eom-pEete dfsintegratfon o f the wall,
It
i s essential t h a t e x c e s - sfvs mot
s t w e penetrat9on be p ~ e v e n t e d , and if thiw f s acrlfeved,then at t h e same t h e the passibll9ty of ,efflorescence o c c w r l n g
will have been almost completely elfmLnatedo
BART
11-
PREVENTTON OF EFFLORESCENCE 1 Contrpl- by- Manufacturers of Masonry Material#The manufacturenaa af masonry materials have not y e t
suoceedsd f n devjlsfng any simple method, capable of general, ap- p l i c a t l o n , to llrnf t; the soluble s a E t s
In
t h e f r products,'Numerous attempts have been made to develop admixtures whfch w u l d combine wfth t h e solwble s a l t s p r e s e n t t o form InsoIubB
compounds, BarSwn carbonate f s one such admfxture Ghf ch has been used and is
stflE
used; however, fnvestfgations to date fndfcata t h a t admfxt;ures a r e n o t completely effectfve f n r e -By
exercising c l o s e controlof
t h e d r y i n g andburning
operations, t h e manufacturers of face-brick have done
much
tor e d u c e
the
possibilityof efflorescence
i n
t h e i r products. F o rexample, c e r t a i n s a l t s t e n d to be decomposed a n d e x p e l l e d from
bricks by hard f i r i n g , and
in
a kiln where c l o s e temperaturecontrol is n o t m a i n t a i n e d , t h e r e mag often be c o n s i d e r a b l e v a r i a t i o n s in t e m p e r a t u r e , r e s u l t i n g in a h i g h e r concentration
of s a l t s in those b r i c k s coming from t h e c o o l e r p a r t
sf
t h e kiln. The r e l a t i v e l y c l o s e c o n t r o l s maintained by t h e face- b r i c k industry in p a r t j u s t i f ythe
c o s t d i f f e r e n c e betweenface-brick and the cheaper clay products, s u c h a s hollow tile
a n d common b r i c k , w h i c h a r e generally u s e d as b a c k i n g materials,
From a n economic s t a n d p o i n t , it is n o t always p r a c t i c a b l e f o r t h e manufacturers of t h e s e c h e a p e r p r o d u c t s to adept the pro- cedures used by t h e face-brick industry.
A t p r e s e n t , the surest preventative of efflorescence
is to keep water o u t o f the masonry. T h i s f a c t o r m u s t be con-
trolled by the architect in d e s i g n i n g t h e building, by t h e can-
t r a c t o r in e r e c t i n g t h e building, a n d by t h e owner in maintaining
and o p e r a t i n 5 t h e b u i l d i n g .
Keeping IYalls Dpy by Proper De-sJgn-
-
and-
- ,Const.ru,ctiqn.Present knowledge of b u i l d i n g construction h a s n o t
r e a c h e d t h e stage xihere t h e problem o f k e e p i n g the w a l l s d r y can be s a i d to be on a satisfactory d e s i g n b a s i s . The problem is complicated by the fact t h a t t h e a p p r o a c h must b e d i f f e r e n t
f o r d i f f e r e n t farms of construction. F a r example, solid walls of dense, n o n - a b s o r p t i v e m a t e r i a l , such a s concrete w a l l i n g , r e q u i r e a different t e c h n i q u e t h a n walls of porous, absorptive m a t e r i a l s , such as b r i c k .
Some of the d e t a i l s which a r e i m p o r t a n t in t h e design and c o n s t r u c t i o n o f masonry walls in general if w a l l s a r e to be k e p t d r y a r e listed below.
F o u n d a t i o n s
( a ) I n s t a l l a d e q u a t e d r a i n s a l o n g f o o t i n g s ,
( b ) Provide membrane waterproofing on t h e outside of foundation walls.
( c ) I n s t a l l damp-proofing in a masonry course im- m e d i a t e l y above g r a d e .
Walls
Above Foundation?( a )
Start
theftrst
c o u r s e ofmasonry
unitswell
awayfrom contact with t h e e a r t h and extend r a i n water
l e a d e r s t o the ground to a v o i d s p l a s h i n g the brickwork,
( b ) Protect w a l l s under construction to p r e v e n t rain or melting snow from entering, When masons a r e not w o r k i n g , cover the t o p of the w a l l s with
weighted tarpaulins, overhanging one or t w o feet on each side.
Bricks
stored on t h e j o b shoulda l s o
be k e p t d r y .Ec)
A m o r t a r p o s s e s s i n g a high degree of w o r k a b i l i t yand water retentiveness should be u s e d , S l a k e d quicklime putty a n d a number sf hydrated l i m e s
have
such characteristics andwill
assure a s a t i s -factory mortar if used in quantities up t o 2 p a r t s lime s o l i d s to
I
of cement. Workability will be improved by the use of well-graded, clean sand w i t h a f i n e n e s s modulussf
about 2.2. The m o r t a r should be a c c u r a t e l y p r o p o r t i o n e d and be mixed f o r at least 2 minutes in a mechanical b a t c h mixer. Pjiortar t h a t is between5
and 2hours o l d w i l l have the most p l a s t i c c h a r a c t e r i s - t i c s .
A l l j o i n t s in masonry w a l l s s h o u l d be f i l - l e d . Joints should
be
concave t o o l e d , first while q u i t e s o f t and a second t i n e when t h e m o r t a rstarts to stiff en.
( d )
If
possible, a b r i c k w i t h a 24-hour cold a b s o r p - tion of between4
andLO
perc e n t
should bes e l e c t e d . Although moisture-proof w a l l s can b e built w i t h b r i c k s h a v i n g
an
a b s o r p t i o n lower t h a n4
p e r c e n t or h i g h e r than 10 p e r c e n t ,t h e h a z a r d s are i n c r e a s e d , and extra precautions must be
taken,
( e )
It
i s p r e f e r a b l e t h a t bricks be kept and laid dry,but if b r i c k s are used with
an
a b s o r p t i o n h i g h e r than 1 0 p e r c e n t , they s h o u l d be wetted. T h i s moisture may c a r r y s o l u b l e salts t o the surfaceof
t h e masonry and t h e r e b y contribute to efflo- rescence; but w e t t i n g the bricks will prevent themfrom absorbing excessive moisture from t h e mor- t a r , which would have t h e more
serious
consequenceof reducing the ultimate w a t e r - t i g h t n e s s of t h e w a l l .
If
it i s necessary t o wet t h e bricks, t h e y shouldbe w e t t e d as uniformly as possible 2 4 to
4€!
hoursin advance of the time needed f o r use, and t h e pile s h o u l d be k e p t covered with a t a r p a u l i n to
prevent l o s s of moisture.
B r i c k s should never be w e t t e d in f r e e z i n g weather.
[f]
On some building projects it may be c o n s i d e r e dd e s i r a b l e to make a chemical analysis of t h e b r i c k ,
L . A . P a l m e r s t a t e s in Technological P a p e r No. 370
of the
U.
3 . Bureau o f Standards that abrick
c o n t a i n i n g
Q 0 0 5
per c e n t or less of water-soluble sulphuric anhydride in its o u t e rl j 8
i n c h of ex-posed surface, is not a p t to contribute to efflo-
rescence.
A t e s t which is mare r e a d i l y performed t h a n chemical analysis is t h e wick t e s t , o r i g i n a l l y d e s c r i b e d in Research Paper iqo, 1015
of
theU.
3 . K a t i o n a l Bureau of S t a n d a r d s by Messrs. McBurney and P a r s o n s . A summary of this test is included %n Appendix 11 of the Tentative Nethod o f Testf o r S u c t i o n and Efflorescence of
Brick,
A . S , T . 2 < , DesignationC67-42T.
( g )
Avoid
forming a water t a b l e e f projecting bricks,To
c o r b e l out w i t h one o r more c o u r s e s of b r i c kor
any o t h e rmasonry
material i s always a danger-ous procedure unless the projecting eouYses are so situated as to' be protected f r o m exposure to moisture p e n e t r a t i o n .
(h) Provide adequate drips on cornices, chinney c a p s , sills, and other masonry projections. G ~ o o v e s s h o u l d b e at l e a s t
r/$
inches w i d e and3/$
inches deep, a n d projections s h o u l d beat
l e a s t 2 inches to keep the d r i p away from t h e w a l l .(i)
Non-corrosive metal o r bituminous f l a s h i n g s h o u l d b e placed under cornices, chimney c a p s , s i l l s and( j ) Caulk around v5ndows and door frames.
(k)
Use l u g s i l l s at windows a n d wherever p r a c t i c a l a v o i d joints in s i l l s .(1) Flash the washes o f pediments and dormers.
( m )
When h i g h humidities may be present w i t h i n masonry buildings careful consideration should b e given to the c o n t r o l of water vapour flow in o r d e r thatc o n d e n s a t i o n may b e prevented
i n
c o l d weather,C o n d e n s a t i o n may be p r e v e n t e d by t h e c a r e f u l
s e l e c t i o n and a p p l i c a t i o n of vapour b a r r i e r s , a n d where p o s s i b l e by the provision sf v e n t i l a t i o n
to remove vapour-laden air, Parapets
( a ) The u s e of p a r a p e t walls s h o u l d b e a v o i d e d when- ever possible,
If
they must be used, t h e y s h o u l d be c o n s t r u c t e d 1 6 t h g r e a t care, u s i n g goad q u a l i t ymaterials, F l a s h i n g s h o u l d cover t h e back side of p a r a p e t
walls
but it should be free-standing,in o r d e r that there may b e circulat5on of air in t h e space between f l a s h i n g and
wall,
(b) A c o p i n g of low permeability
and
good frost r c s i s - t a n c e s h o u l d be used, and this coping should havea
t h r o u g h f l a s h i n g under it extending at l e a s tE
inch
past the f a c e of t h e w a l l on efther s i d e .3 .
Keeping Walls .-
D r y -. by-_Careful Mainteng>,"c-ce.Walls
my be p r o p e r l y built, b u t t h e y must also beproperly maintained t a s t a y dry.
It
is especially i m p o r t a n t thatf l a s h i n g s , g u t t e r s , dovimspouts and copings be k e p t in good s t a t e of repair and t h a t c r a c k e d o r p o o r l y f i l l e d joints be promptly raked out and r e p o i n t e d .
When efflorescence a p p e a r s on t h e walls af
a
b u i l d i n g that has been in service f o rseveral
y e a r s , it is evidence t h a tm o i s t u r e is p e n e t r a t i n g the
walls.
Thesource
o f p e n e t r a t i o n'?The l o c a t i o n o f efflorescence does n o t necessarily
mean
t h a t w a t e r i s e n t e r i n g t h e w a l l at t h a t p o i n t , but f r e - q u e n t l y provides a c l u e to t h esource of
t h etrouble,
F o rexample, s t r e a k i n g from t h e top of a
wall
downo r ,
a t
times,p a t c h e s some d i s t a n c e from t h e t o p , would p o i n t
t o
d e f e c t i v e c o p i n g sor
g u t t e r s .Efflorescence
u n d e r windows would p u t t h e s i l l s a n d caulking around the frame u n d e r s u s p i c i o n . E f f l o -r e s c e n c e on the courses of a f o u n d a t i o n , c l o s e t o t h e ground, e s p e c i a l l y w i t h a r a t h e r p o r o u s brick, would i n d i c a t e ground
water drawn up by c a p i l l a r y suction. A s i n g l e p a t c h o f ef- florescence on a w a l l , w i t h no o b s e r v a b l e r e l a t i o n to masonry
openings, may sometimes b e e x p l a i n e d on the grounds of a b a d l y
defective m o r t a r j o i n t
or
b y a projecting brick forminga
w a t e rt a b l e S t .R
If
a s e r i o u s defecthas
been built into t h ewall,
it w i l l o f t e n be d i f f i c u l t to remedy t h e condition permanently by a s u r f a c e r e p a i r . An error o f omissioncan
be e q u a l l y serious and d i f f i c u l t to remedy. k damp-proof membrane, f o r example,is p r a c t i c a l l y impossible t o i n s e r t after the wall h a s been
b u i l t .
PART 111- RBIQVAL
OF
EFFLORZSCEIiCEWhen efflorescence has resulted from excessive s o a k i n g during csnstructfon, a n d t h e w a l l has f i n a l l y dried out and r e p e l s m o i s t u r e successfully, then t h e efflorescence will g r a d u a l l y b e washed away by t h e r a i n s a n d disappear wi-t;h t i m e . T h i s process may be h a s t e n e d by washing away w i t h water applied w i t h stiff
scrubbing b r u s h e s ; o r , if t h i s is n o t e f f e c t i v e , wet t h e wall with
water,
t h e n scrub w i t h water c o n t a i n i n q not more t h a n10
p e r centof
muriatic (hgdrochlaric)
a c i d and, immediately t h e r e a f t e r , r i n s e thoroughly w i t h p l a i n water.If
muriatic a c i d is used, iti s
particularly i m p o r t a n t that t h e w a l l be wetted w i t h water first,
and it is i m p o r t a n t also that t h e solution s h o u l d not c o n t a i n
more
than
10 p e r c e n t rnuriat5c a c i d .Obviously,
if
moisture is p e n e t r a t i n g a wall due to f a u l t y d e s i g n , c o n s t r m c t i o n , or maintenance, then t h e measuresdescribed above
hi11
b e useless, inasmuch a s t h e efflorescence w i l l reappear. The underlying d e f e c t must first be remedied in order to f i n a l l y b e r i d of t h e efflorescence,- , .--.
-
.-.. ..
A - 2 . * L . . L. -+-&--- - - -
--
A -- + - -R "Brick E n g i n e e r i n g , Handbook o f DesignTt,
H.
C . Plwnmer and L , J ,Reardon;
Structural
Clay P r o d u c t s Institute, h'ashington, D , C ,1943.
P.171.
REFERENCES
(1)
"Principles
o f ModernBuildingw,
Volume
1,
R . F i t z r n a u r i c e ;
H A ,
Stationery Office,
London,1939.
7(2)
17WetWalls
and Efflorescence", A.I
. A .File No.
5m.
-
( d -
+-4
L . A , Palmer; American Pace Brick A s s o c i a t i o n , ,
Chicago, 1928,
-
. . , 1 LL r z ~ ~ n ~ r .-"sL1 L ~ L -
LC-4
e.d' 8 ~ i * .( 3
) "Brick E n g i n e e r i n g , Randbook o f Designt',A . C . B l m e r and
L. J.
R e a r d o n ; Structural Clay Products Pnstitute, Washington,D.
C., 1943.( 4 )
"The Chemistry o f Cement and Concrete",I?.
E,
Lea and C. H. Oesch; EdwardArnold and
Co.,London, 193
5
.
(