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Test and application of the surface-subsurface physically based reactive transport model CATHY on a vineyard hillslope

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HAL Id: hal-02606679

https://hal.inrae.fr/hal-02606679

Submitted on 16 May 2020

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Test and application of the surface-subsurface physically based reactive transport model CATHY on a vineyard

hillslope

Laure-An Gatel, Claire Lauvernet, Claudio Paniconi, Julien Tournebize, S. Weill, Nadia Carluer

To cite this version:

Laure-An Gatel, Claire Lauvernet, Claudio Paniconi, Julien Tournebize, S. Weill, et al.. Test and application of the surface-subsurface physically based reactive transport model CATHY on a vineyard hillslope. AGU, Dec 2016, San Francisco, United States. pp.1, 2016. �hal-02606679�

(2)

Evaluation of the surface-subsurface physically based reactive

transport model CATHY at several scales

Laura Gatel

a*

, Claire Lauvernet

a

, Claudio Paniconi

b

, Julien Tournebize

c

, Sylvain Weill

d

, Nadia Carluer

a

Context

Tools to help to understand and to quantify pesticide transfers in agricultural

watersheds are necessary. Physically based and spatially distributed models can be

particularly useful in representing precisely processes and interactions between the

soil surface and subsurface and thus in evaluating landscape mitigation elements

management.

1- Implementation of reaction in the CATHY model

Flow

1D diffusive wave

Transport

1D Advection

Flow

3D Richards

Transport

3D Advection

Coupling procedure

Surface

Subsurface

Reactions

Linear adsorption

First order decay

2 – Evaluation of surbsurface part of the new CATHY model on laboratory data

The laboratory MASHYNS tool :

Irstea Antony

Experimentations on MASHYNS : four rain periods with three 2-hours solute inflow (batch 1, 2 and 3). For each batch, specific solutes and one tracer are used.

Comparison of observations and CATHY simulations without calibration

A Morris sensitivity analysis for 4 solutes (batches 1 and 2)

Examples of the sensitivity analysis results for breakthrough timing and peak concentration :

Kd DT50 (j) BATCH 1 Clomazone 5.7 89 Imazamox 0.3 70 BATCH 2 Isoproturon 2.32 12 Mesosulfuron 1.77 45 BATCH 3 Bentazone 0.72 45 Sulcotrione 0.68 25

→ Except for clomazone, all evaluations are between acceptable and good

→ Yet for all simulations, breakthrough delay is non negligible

→ Ksh, Ksv, n, θs and Kd are the most

influent parameters

→ For Imazamox, Kd has a poor

influence compared to the other solutes

Major effects

3 – Test of the new CATHY model on a vineyard hillslope

Study site :

a 150-m long vineyard hillslope

along the Morcille river (Beaujolais, France).

The study will use data from a natural

rain/runoff event.

Vegetative buffer strip :

a transfer

mitigation landscape element involving

complex processes interactions

Aerial view of the vineyard hillslope and corresponding domain as used in CATHY (1 m x 1 m mesh and 25 layers)

NSE = 0.795 RMSE= 0.142

Model evaluation, example for sulcotrione :

Saturated conductivity Ksh m.s-1 LN (9x10-5 ; 1) Ksv m.s-1 LN (5.62x10-5 ; 1) Porosity θs - N (0.47 ; 0.047) VG parameter n - N (1.8 ; 0.18) α cm-1 N (0.012 ; 0.0012) Initial rain IC m.s-1 U (2.5x10-7 ; 3x10-7) Decay coef λ d N (70 ; 21) Sorption coef Kd - N (0.3 ; 0.06)

Exemple with sulcotrione

→ Delay and mass balance have been improved

and the FITEVAL evaluation leads to « very

good »

Reaction parameters for the 6 studied solutes

1m3 homogeneous soil 50 % loam + 50 % sand Measured parameters, Controlled conditions No macropores, Low dispersion

Real field situation : not all

parameters are well-known.

The runoff repartition is complex

(“rases” : small ditches which

artificially gather surface runoff).

Solute exchange between surface

and subsurface is complex.

The upscaling (compared to

MASHYNS) will increase

computing costs.

+

+

+

=

Challenging

simulation !

Conclusion & perspectives

On the CATHY model with reactive transfers :

The performed tests and the sensitivity analysis based on MASHYNS data validated the

subsurface part of CATHY reactive transfers version : ability to reproduce observations,

robustness regarding to parameters variation.

On the hillslope modeling :

The field is ideal to study complex processes and thus represents a major challenge for

CATHY with reactive transfers. Additionally, some existing processes are not explicitly

represented (macroporosity, diffusion and dispersion) and we will verify CATHY's ability

to globally report major processes at the hillslope scale. The aim is not to reproduce

exact observations, but more to analyse model's results on chosen synthetic cases.

With the financial participation of :

Objectives :

- To better understand reactive solute transfers at the

hillslope scale, in particular surface / subsurface

interactions

- To deepen the expertise on the CATHY model

Drained system

The evaluation was performed with the FITEVAL tool (Ritter 2003) which assesses several criteria and associated uncertainty.

Selection of an efficient parameter set and

application on two solutes (batch 3)

Simulation results and observations on cumulative output mass for each batch

Interaction or non linear effects

a-Irstea, UR MALY, 5 rue de la Doua, 69100 Villeurbanne, France (*corresponding author: laura.gatel@irstea.fr), b-INRS, centre Eau-Terre-Environnement, 490 rue de la Couronne, Québec (Québec) G1K 9A9, Canada.

c-Irstea, UR HBAN, 1, rue Pierre-Gilles de Gennes, 10 030 Antony, France. D-LhyGes, 1, rue Blessing, 67000 Strasbourg, France.

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