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Impact of technological post-harvest processing on the production of chocolate aroma compounds in raw cocoa beans originated from Côte d'Ivoire

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Impact Of Technological Post-Harvest Processing On

The Production Of Chocolate Aroma Compounds In Raw

Cocoa Beans Originated From Côte d’Ivoire

a Department of Food Science and Technology, University of Nangui Abrogoua, 02 Bp 801 Abidjan 02, Côte d'Ivoire b UMR Qualisud, CIRAD - TA-B 95/16, 73 rue JF Breton, 34398 Montpellier Cedex 5, France

M. Koumba Konéa, P. Bony Koffia, S. Tagro Guéhia, M. Lebrunb, N. Durandb, A. Fontanab, D. Montetb, R. Boulangerb

Ivorian raw cocoa material is currently characterized by a standard aroma quality. Fermentation is one of

the major post-harvest treatments leading to the production of chocolate aroma compounds. This

research aims to study the effect of each post-harvest processing stage on the development of flavor

compounds in raw cocoa beans.

Material and Methods

Cocoa beans were extracted from mixed Ivorian 1st genera6on of hybrids (Amelonadao x West African Trinitario)

cocoa pods. They were prepared at South East of Côte d'Ivoire according to controlled pod opening delay, methods and 6me of fermenta6on, turnings of fermen6ng beans and sun-drying (Figure 1). A total of twelve fermenta6on processes were realized. In each fermenta6on process, three samples were prepared and analysed in triplicate. Vola6le aroma compounds were analyzed by SPME-GC-MS method and sta6s6cal analysis of data were done by ACP.

Conclusion

Afoakwa, E. O., Pa terson, A., Fowler , M., & Ryan, A. ( 2008). Flavor formation a nd character in coc oa and chocolate: a c ritical review. Critical Rev iews in Food Scien ce and Nutrition, 48(9), 840-857 Rodriguez-Campos, J., Escalona-Buendía, H. B., C ontreras-Ramos, S. M., Or

ozco-Avila, I., Jaram

illo-Flores, E., & Lug o-Cervantes, E. (2012 ). Effect of ferme ntation time and drying temperature on v olatile compound s in cocoa. Food c hemistry, 132(1), 277-288. Rodriguez-Campo s, J., Escalona-Bue ndía, H. B., Orozco -Avila, I., Lugo-Cervantes, E., & Jaramillo-Flores, M. E. (2011). Dynamics of volatile and non-volatile compounds in cocoa (Theobroma cacao L.) during

fermentation and

drying processe

s using principal compone

nts analysis. Food

Research Interna tional, 44(1), 250-258.

Referenc

es

Results

• A total of 30 aroma compounds grouped into six chemical compounds families were detected (Table I). • Fermented cocoa beans from 2 days opening delay pods contained more aroma compounds than cocoa from 8 days opening delay pods (Figure 2).

• Like turning of fermen6ng beans, fermenta6on technique (Figure 3) did not influence the forma6on of aroma compounds in raw cocoa beans. • The analyse of importance of fermenta6on's day was realized on each pod delay. For the first delay, the fermented cocoa a`er 2 days were characterized largely by alcohol aroma compounds while 6 and 7 fermented cocoa contained aroma compound belonging to several chemical families (Figure 4). • We observed the same conclusion for the second delay pods, but a`er two days, in addi6on of alcohols; some esters (ethyl acetate, isobutyl acétate 2 and 3 methylbutyl acetate) were also most abondant. C onception: Cir ad, Mar tine Dupor tal, June 2017 — ©  photos Maï K oumba K oné

Formation of aroma compounds in raw cocoa beans is depending both on the

pods opening delay and the fermentation time but not on the fermentation

method neither turning of beans.

Figure 2. Graphical representation of Principal component analysis (PCA) of the volatile flavor compounds

content in cocoa beans of 2 and 8 day pod storage

Table I. Aroma compounds identified in cocoa beans samples

Figure 1. Sampling during post-harvest processing of cocoa

Figure 3. Graphical representation of Principal

component

analysis (PCA) of the volatile flavor compounds content in cocoa beans fermented according to different methods Figure 4. Graphical representation of Principal component analysis (PCA) of the volatile flavor compounds content in cocoa beans of 2 day pod storage according to the duration of fermentation

Recommendation

In order to improve raw cocoa aroma quality, pods must be opened for 2 post-harvest days and beans fermented for at least 4 days.

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