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A study of the effect of holding time on the crystallization of ZnO-Al2O3-SiO2 glass

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A study of the effect of holding time on the

crystallization of ZnO-Al

2

O

3

-SiO

2

glass

Amina Grabsi , Abdellah Chorfa

The Institute of Optics and Precision Mechanics, Farhat Abbas University, Setif, Algeria. aminagrabsi.ufas@gmail.com

Abstract—Glass ceramics materials were prepared from a ZnO-Al2O3-SiO2 glass, these glasses were heat treated at 890°C during

2,4 and 8 hours. An optical study using a Scanning Electron Microscopy, and Spectro-colorimetry were carried in order to find the effect of the holding time on the crystallization of this glass.

Keywords—Glass-ceramic, Crystallization, SEM, Colorimetry

I. INTRODUCTION

Glass-ceramics are polycrystalline materials formed by controlled crystallization of the glass with a designed schedule of heat-treatment, exhibiting a number of outstanding characteristics in comparison with the traditional ceramics and glasses and a wide range of exciting potential applications [1-2].

In this work the effects of the holding time on the crystallization behavior of ZnO-Al2O3-SiO2 glasses were

investigated with a scanning electron microscopy, and Spectro-colorimetry.

II. Experimental

Three samples of ZnO_Al2O3_SiO2_CaO_ Na2O glass have

been heated at 890°C for 2,4 and 8 hours in an electric oven, with the rates of heating and cooling from room temperature to the holding temperature and conversely, in each heat treatment performed were 2 °C min-1 and 5 °C min-1

respectively.

The crystallization behavior of glasses was studied using a Hitachi S-4700 Field Emission Scanning Electron Microscope (FE-SEM). Also, the L * a * b* measurements of these samples were made with a Konica Minolta CM-2600 Spectro-colorimeter.

III. Results and Discussion

L*, a*, b* coordinates of each sample (A, A2, A4, and A8 which are respectively the original glass and the glasses heated for2,4, and 8 hours) which indicates color differences, are shown in Table 1. Samples tended to be white and the A8 sample is the whitest.

TABLE I. L*, a*, b* data of the samples.

Sample A A2 A4 A8

L* 24.225 32.285 33.99 74.285

a* 0.65 -0.635 -0.635 -3.83

b* 10.52 5.43 5.845 3.41

SEM micrographs of the three heated samples are presented in Figure 1, Figure 2, and Figure 3 with different magnification for each one. On the first glass A2 (Figure 1) the crystallization reached only the surface layer of the sample. On the other hand, in sample A4 (Figure 2) a dense and homogeneous crystallization with smaller crystals. when in Figure 3 it shows that the A8 glass has also a dense and homogeneous crystallization but in this one with a large size of crystals. the crystals that appear in the three treated glasses are of the Wollastonite [3] type.

FIGURE 1. SEM images of the glass-ceramic heated for 2 hours

(A2)

FIGURE 2. SEM images of the glass-ceramic heated for 4 hours

(A4) 1.00 mm 30.0 µm 5.00 µm 5.00 µm 20.0 µm 100 µm

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FIGURE 3. SEM images of the glass-ceramic heated for 8 hours

(A8)

IV. Conclusion

In this work, a white glass ceramic was found. As well as a description of the crystallization behavior of the glasses and the impact of the holding time on this phenomenon was made, in order to give the best performance in terms of glass ceramic production.

ACKNOWLEDGMENT

I’am grateful to glace and ceramic institute at which I could do my research

REFERENCES

[1] S. Yılmaz, G. Bayrak, S. Sen, and U. Sen, “Structural characterization of basalt-based glass–ceramic coatings,” Mater.Des. vol. 27, pp. 1092– 1096, 2006.

[2] Z. Yang, Q. Lin, S. Lua, Y. He, G. Liao,” Effect of CaO/SiO2 ratio on the preparation and crystallization of glass-ceramics from copper slag,” Ceramics International, vol. 140, pp. 7296–7305, 2014.bers,

ISMRE2018/XXXX-2018 ALGERIA

5.00 µm

20.0 µm 100 µm

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Figure

FIGURE 1. SEM images of the glass-ceramic heated for 2 hours  (A2)
FIGURE 3. SEM images of the glass-ceramic heated for 8 hours  (A8)

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