Adsorption of nitric oxide and temperature programmed desorption on nonstoichiometric nickel-copper manganites
9
0
0
Texte intégral
(2) Open Archive TOULOUSE Archive Ouverte (OATAO) OATAO is an open access repository that collects the work of Toulouse researchers and makes it freely available over the web where possible.. This is an author-deposited version published in : http://oatao.univ-toulouse.fr/ Eprints ID : 11643. To link to this article : DOI:10.1016/S0169-4332(01)00180-5 URL : http://dx.doi.org/10.1016/S0169-4332(01)00180-5. To cite this version : Drouet, Christophe and Alphonse, Pierre and Fierro, José Luis García and Rousset, Abel Adsorption of nitric oxide and temperature programmed desorption on nonstoichiometric nickelcopper manganites. (2001) Applied Surface Science, vol. 174 (n° 34). pp. 289-295. ISSN 0169-4332. Any correspondance concerning this service should be sent to the repository administrator: [email protected].
(3)
(4) ! .
(5) ! !! " #
(6) " $!% "" #& ' () " # * ""+,) ")" '- ## .. Abstract (
(7) ) " ' *(+
(8) ,
(9) ) '
(10) ! " ' " ' ,- ) " ( " ' " ' ,- ) ) . " " / " )
(11) (
(12) ,- ) * ) $%%8+ ' ,- *0%1%2+ ( ,$- ) ) $%%8 " $3%8 (
(13) . 4
(14) /*0"#1 6 & , & ,-& & ( . 1. Introduction , 4 ,&*. *9 & *+&9d/:-:d " ' " 4 '
(15) ) )
(16) ;#< ( ' " * = " #%% $/+ 4 = ( '
(17) ' 4 )
(18)
(19) 4 " ,9 . 9 . : '
(20) ,$ . $ . . 9 " '
(21) ' 4 ) >
(22) " )
(23) ' " . "
(24) ' ' ' 4 " ' d *d ' ) %$% %?%+ !
(25) ;$< " ) " " ,- - )
(26) @4 " ) " A "' ) ,- * B) 4 + .
(27) *(+
(28) " . ) ' 7I5!6 J. :$# @4 . 2. Experimental. 3. Results. ! 2&# ..". $! #"." "3 ) "&#. ( ,&*. *9 & *+&9d/:-:d ) ' ' 4 93%8 D
(29)
(30) @ * ;9< + ( " . ' = ( # #"." "3 ) "&# ( ) >4' *@H+ " -$ *$%2+/ *?%2+ 9%%8 # 4 ) $%8 B) ) ' (
(31) ) 4. 1%% ,-/ B) D% 9/ :% ) )
(32) $ ,. ."4,,# #"." "3 ) "&# ( (
(33) ) ' 4 ' ,-4 b 38/ . ( # " ' d "
(34) . *$/+. d. ,%$3. $03&9d/:-:d ,%0%. $9%&9d/:-:d ,%$3%?%. #13&9d/:-:d ,%0%%D3. #D3&9d/:-:d ,%0%%1#. #91&9d/:-:d. #D3 #?% #3% #D% #:%. %:? %D3 %:% %$0 %$$. . %%9 %%3 %%9 %%$ %%$.
(35) " 4 ) G ,= 9% : " ' ,- K ) . ) ' LL ! 1%% ,-= ! MM
(36) ,%0%%D3. #D3&9d/:-:d * #+ ( ) ,- *,= 9%+ K *,= :+ ) ,- * LLMM+ ) )
(37) ,-. ) ' ,- * LLMM+ ) ,- B) ) ' B) #3%% ) * ) " + $%%% ) ' @ " 4 4 $ ,. ."4,,# #"." "3 ) "&# 4 B) ) ' ) ' ' (
(38) ' " . ,= 9% * ,-+ ,= :: 9$ * " 4
(39) ' + ) " , " ,= #$ * + ) " ) -$ ,= :: '
(40) ,$- , 4 * ,-$ ,$+ ) $ ! 5"."
(41) 2 ,") (
(42) ) 4 .
(43) # ,- *1%% ,-/ D% 9/ + $38
(44) ,%0%%D3. #D3&9d/:-:d. " * $+ 6 " ) " G ) * *#+ *$++ ) ' .
(45) ' = 33 ?%8 " #%%8 '4 = ) . ' ) " " 4. $ ( 4
(46) ,- .
(47) 9 5" ,- *#+ *$+. " . ' ;:3< G = )
(48) " * ' 4 + )
(49) *
(50) ;
(51) * ;+ ; #< *) ; & &
(52) +/0 ) LL&
(53) MM
(54) LL0MM )
(55) *AK.+ + ( *#+ *$+ ) * 9+ ) &,
(56) ' "
(57) " ** > %:D3+. $ 5"."
(58) 2 ,") ( ,$- *,= ::+ . . * :+ 4 = ) C ,$- LL) MM *3%$%%8+ ,$- LL MM *$03:%%8+ K @ ' ,$- ) &, '
(59) ,%0%%1#. #91&9d/:-:d 4 ,$- ) " 9%38 * ) :+ $ $ <,"#"." "3
(60) 2 3" #? 2$ .# "&# G ' * 4 " +
(61)
(62) ,- ) *,%0%%D3. #D3&9d/:-:d+ ) 32 #? -$ / #3%8 $% 4 = ,= 9$ * 4 ,#? - #D -$ + ,= 9: * #D -#? -+ ) * 3+ 4 " " ,= 9% ,- ( ' ,= 9$ 9: $$38 - ' ,= 9: ) " $%$%%8. : ( 4
(63) ,$- .
(64) 3 5" ,= 9% 9$ 9: ,- 4 *b 38/ +
(65) ,%0%%D3. #D3&9d/:-:d ) #? -$ . 4. Discussion. ,- ) ( ) ' . ,- C " ' 4 " ' ( ,- " ' " ' ' LLMM LL MM " ' . " *( $+ ( 4 ) 4
(66) *,%$3. $03&9d/:-:d ,%0%. $9%&9d/:-:d+ " ' " ' ,- ' )
(67) ( ) "'
(68)
(69) ;$< ) ,- " 4
(70) . 9-: ( . K )
(71) ( ,- " " ) 4 ) ,- ) ) * LLMM+
(72) ) ) "
(73) ) "'
(74) ' , ( @ ) $%%% ) ,- B) ) LL,-= ! MM ,- ) ) " . ) LLMM ) ) " ( " . ( $ ' " ' " ' ,-
(75) -
(76) &,. *. ,(' #%. %$3 %$3 %0% %0% %0%. % %?% % %D3 %1#. #: #% $: #1 ##. :. /. G " ' #%. D. %?3 %D0 #99 ##1 %01. /$. #% #% %: #3 #$ %3. :. /. ! " ' #%. D. %D# %$1 %?D %09 %9?. /$. #% %: %D %1 %0 %D. :. /. #%. D. %$: %9? %:? %:D %:#. /$.
(77) =
(78) " ) " ' " ' ,- ) ) " / " ( ' ' ) , ( . ) ' ,- C , ,- > . ,- > , 4
(79) ' " ,= 9% :: , ,$- (
(80) ' *
(81) .
(82) ' + ) ,- $%8
(83) " ( ,- ) 338 * $+ " ) ' " ' ) . ;D< ( . . " ;01<C *+ & *+. " & / *+
(84) ) 4 " " ' ,- " ( "
(85) " ) * 9+ ' *#+ *$+ ) ( )
(86) " )
(87) ' . ' . ) ,- ( ,$- ) " * :+ ( = " ) C ,$- ) *3%$%%8+ ,$- *$03:%%8+ G )
(88) " ( ,
(89)
(90) ' ' . ;#%< ,$- ) -
(91) 4 ' ' "'" ;##< $-9 ' ,$- 4
(92) )
(93) ' ) . /
(94) ( ,$- 9%38 4
(95) ' ' = ' N6 ' ;#$< ( )
(96) *( 9+ )
(97) ' ,- )
(98) A ,- )
(99) ) 32 #? -$ /
(100) ,#? - *,= 9$+ #D -#? - *,= 9:+ ) " ) $%%8 ,- * 3+ $$38 ,= 9$ *#D -#D -+ ,= 9: *#D -#? -+
(101) '
(102) ;9< ( #D -#? -
(103) ' #D -
(104) . " '
(105) ) #? - #? -$ K ,#? - , *$%$%%8+ = ( 9 ,-
(106) -
(107) . ,%9%. $0%-:d ,%0%. $9%-:d ,%0%%D3. #D3-:d ,%0%%1#. #91-:d . . ,- */+ #% #3 #$ %3. G " ' ,-. . #% #% #% #%. : : : :. . ,- *2+ ,-. ,$-. D? ?% ?? ?D. 9$ $% #$ #:.
(108) $%8
(109) " . . 5. Conclusions. References.
(110) ,&*4 . *9 & *+&9d/:-:d ) ) ' . ,- C " 4 " ( " ' " ' ,- .
(111) C ) &, ) * . " " / " ) ( ' ) ,- . (
(112) " ) "
(113) ' ,- ) *3%$%%8+ #%9%2 ,- ,$- () ,$" " C ) *3%$%%8+ *$03:%%8+ ( ' . ;#< ! 7C 5 " ;$< ! G 6 $$3 *$%%%+ ::% ;9< ! 6 6 G #$9 *#111+ $3 ;:< ! 8 #$ *#1D$+ $%9 ;3< 8 #$ *#1D$+ $:3 ;D< 6 " .@ H G ! H4! 4 !H 6 G $% *#119+ #%D0 ;0< ( ) A C !7 ( ) *5+ 5
(114) . ' ! 8 9 , ) O #10D ;?< ( . , ) O #10? ;1< . ( A ( . K ' 8K , ) O #110 ;#%< ( >" ?1 *#1?:+ 9#: ;##< "'" O " O. 6 P #1 *#10?+ 39$ ;#$< ' ! G G . $ *$%%%+ :#1.
(115)
Documents relatifs
Impact of pre-transplant diffusion lung capacity for nitric oxide (DLNO) and of DLNO/pre- transplant diffusion lung capacity for carbon monoxide (DLNO/DLCO) ratio on pulmonary
Figure 2 and Table SI 1 shows the effect of pH and temperature on MB and MO adsorption capacities of the four ACs when the initial dye concentration C 0 was fixed to 10 mg/L.. MB is
The experimental adsorption capacity, Qe (mg/g) of rGO for DEP and DEHP was calculated according to eq. All the experiments were run in triplicate to ensure the
Summarizing the neutron scattering and adsorption isotherm measurements, four first order phase transitions, namely p solid = à solid, fi solid e a liquid, y solid #