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Sampling with discrete contamination

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This is an author-deposited version published in :

http://oatao.univ-toulouse.fr/

Eprints ID : 5522

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OATAO is an open access repository that collects the work of Toulouse researchers and

makes it freely available over the web where possible.

To cite this document : Lyman, Geoffrey and Bourgeois, Florent

Sampling with discrete contamination. In: 5th World Conference

on Sampling and Blending (WCSB5), 25-28 Oct 2011, Santiago,

Chile.

Any correspondence concerning this service should be sent to the repository

(2)

23 Geoffrey J. Lyman

Materials Sampling & Consulting, Australia Florent S. Bourgeois

Materials Sampling & Consulting Europe, France

Sampling with discrete contamination

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INTRODUCTION

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(4)

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Figure 1 Illustration of disposition of samples and slugs of contaminated material

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Table 1 Simulation results for sampling with discrete slugs of contaminant (10 000 simulation)

Case 1 2 3 4 5 6 7 8 V)5,%$@mA ST ST ST ST ST ST ST ST N+/.#'#+2%$@nA PTT STT PTT STT PTT PTT PTT PTT V)5,$%*[#$@uA T=TTTP T=TTTP T=TTTP T=TTTP T=TTTb T=TTbT T=TTQT T=TTP N+/.#'#+2$%*[#$@vA T=TTTb T=TTTb T=TTTP T=TTTP T=TTTP T=TTTP T=TTTP T=TTTP V&'()#$0.&/2*1+$hci b=T PT=T P=T S=T P=T P=T P=T P=T V)5,$/1+/$@((:A PTTT PTTT PTTT PTTT STT ST QQ PTT D-#.&,#$/1+/$@((:A S S S S S S S S

D-$/1+/$@%*'5)&2*1+A S=TP P=ej S=Tk P=ee P=ed P=eP P=ef P=ek

OVI$2"#1.8 T=efT T=dfb P=jPS P=SkP T=efT T=SSS T=QQe T=dbj

(8)

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Figure 2 Histogram of sample concentrations and cumulative distribution from simulation, Case 1

Figure 3 Histogram of sample concentrations and cumulative distribution from simulation, Case 2

Figure 4 Histogram of sample concentrations and cumulative distribution from simulation, Case 3

(9)

Figure 5 Histogram of sample concentrations and cumulative distribution from simulation, Case 4

Figure 6 Histogram of sample concentrations and cumulative distribution from simulation, Case 5

Figure 7 Histogram of sample concentrations and cumulative distribution from simulation, Case 6

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(10)

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Figure 8 Histogram of sample concentrations and cumulative distribution from simulation, Case 7

Figure 9 Histogram of sample concentrations and cumulative distribution from simulation, Case 8

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(11)

where mI *%$2"#$*+/.#'#+2$'&%%$*+$C,?$T *%$2"#$'&%%$413$*+$2("?$w$*%$2"#$&(#.25.#$*+$'#2.#%$ &+9$s *%$2"#$/5R#.$%(##9$*+$'l%=$!"#$.#%5)2$*%^ 5 = 5 = STTT T=TPe Q=d T=b SP=P I m (22) D%%5'#$2"&2$&+$*+/.#'#+2$*%$2&C#+$#-#.8$fT$%#/1+9%$&+9$2"&2$&$%&'()*+,$5+*2?$L, /1..#%(1+9%$ 21$STTT$21++#%$10$,.&*+=$!"#.#$&.#$2"#+$eT$*+/.#'#+2%$2&C#+$95.*+,$2"#$%&'()*+,=$!"#$0.&/2*1+$ 10$2"#$%&'()*+,$5+*2$2&C#+$&%$(.*'&.8$*+/.#'#+2%$*%^ = 5 = 5 = d eT SP=P S=T PT T=TTTeb I nm f L (23) where L, 2"#$#E2#+2$10$2"#$%&'()*+,$5+*2$*%$2&C#+$&%$STTT$21++#%=$!"*%$%&'()*+,$(.121/1)$*%$ 2"#$1+#$9#<+#9$:8$2"#$g&+&9*&+$F.&*+$g1''*%%*1+$01.$3"#&2$%&'()*+,$@g&+&9*&+$F.&*+$ g1''*%%*1+?$STTeA= m#E2?$&%%5'#$2"#$&-#.&,#$)#-#)$10$/1+2&'*+&2*1+$*% c=PT((:$&+9$2"#$&-#.&,#$/1+2&'*+&2*1+$ )#-#)$*+$&$%)5,$*%$cT=PdTT((:=$n#2$2"#$%)5,$1//5(8$&$-1)5'#$10$2#+$)*2.#%$&+9$3#*,"$j$C,=$ !"#+$2"#$+5':#.$10$%)5,%$'5%2$:#^ = T cL m c u (24) %1^ 5 5 = 5 = d PT S PT PdTT j PbdQ m (25)

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(12)

Figure 10 Histogram of sample concentrations and cumulative distribution from simulation, design study

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Figure 11 Random slugs for one realisation of the design example

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Figure 12 Concentration as a function of time for 22 tonne slugs (portion of data set)

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(13)

VARIOGRAMS OF CONCENTRATION N+$,#+#.&)?$2"#.#$*%$+1$&+&)82*/&)$#E(.#%%*1+$01.$2"#$-&.*1,.&'$10$/1+/#+2.&2*1+=$>13#-#.?$ 3"#+$2"#$%)5,$%*[#$*%$%'&))$&+9$2"#$+5':#.$10$%)5,%$*%$+12$211$)&.,#$@")#''#PA?$2"#.#$3*))$:#$ &)'1%2$+1$1-#.)&($10$2"#$%)5,%$&+9$2"#$%)5,%$01.'$&$\11)#&+$.&+91'$%#2=$N+$%5/"$&$/&%#?$*2$*%$ C+13+$2"&2$2"#$-&.*1,.&'$.*%#%$0.1'$[#.1$21$&$%*))$10^

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(14)

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(15)

APPENDIX A – THE VARIANCE OF THE SAMPLE CONCENTRATION

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(16)

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Figure

Figure 1  Illustration of disposition of samples and slugs of contaminated material
Table 1  Simulation results for sampling with discrete slugs of contaminant (10 000 simulation)
Figure 7  Histogram of sample concentrations and cumulative distribution from simulation, Case 6
Figure 9  Histogram of sample concentrations and cumulative distribution from simulation, Case 8
+2

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